0000000001309708

AUTHOR

Thuy Minh Dau

showing 4 related works from this author

Ferrocenyl-functionalized tetranuclear gold(I) and gold(I)-copper(I) complexes based on tridentate phosphanes

2013

Tetranuclear AuI–FeII dimetallic and AuI–CuI–FeII trimetallic complexes bearing ferrocenyl (Fc) groups have been assembled by using two triphosphane ligands, namely, (PPh2CH2)2PPh (dpmp) and (PPh2)3CH (tppm). The compositions and structural type of the clusters are dependent on the stereochemistry of the P donor ligands. The complexes [tppmAu3Cu(C2R)3]PF6 [R = Fc (1) and 4-C6H4-Fc (2)] adopt a trigonal pyramidal {Au3Cu} arrangement of the coordinating metal core, whereas for the compounds with the linear triphosphane [Au4(dpmp)2(C2R)2](PF6)2 [R = Fc (3) and 4-C6H4-Fc (4)], a planar rhomboidal {Au4} framework was found. Clusters 1–4 were characterized by NMR spectroscopy and ESI-MS measureme…

ChemistryStereochemistrychemistry.chemical_elementTrigonal pyramidal molecular geometryNuclear magnetic resonance spectroscopyElectrochemistryRedoxCopperInorganic ChemistryMetalElectron transferchemistry.chemical_compoundCrystallographyTriphosphanevisual_artvisual_art.visual_art_mediumta116European journal of inorganic chemistry
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CCDC 937899: Experimental Crystal Structure Determination

2013

Related Article: Thuy Minh Dau, Julia R. Shakirova, Antonio Doménech, Janne Jänis, Matti Haukka, Elena V. Grachova, Tapani A. Pakkanen, Sergey P. Tunik, Igor O. Koshevoy|2013|Eur.J.Inorg.Chem.||4976|doi:10.1002/ejic.201300615

bis(mu~3~-bis((Diphenylphosphino)methyl)phenylphosphine)-bis(4-(ferrocenyl)phenylethynyl)-tetra-gold bis(hexafluorophosphate) unknown solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 937897: Experimental Crystal Structure Determination

2013

Related Article: Thuy Minh Dau, Julia R. Shakirova, Antonio Doménech, Janne Jänis, Matti Haukka, Elena V. Grachova, Tapani A. Pakkanen, Sergey P. Tunik, Igor O. Koshevoy|2013|Eur.J.Inorg.Chem.||4976|doi:10.1002/ejic.201300615

Space GroupCrystallography(mu~3~-tris(Diphenylphosphino)methane)-tris(mu~2~-eta^2^-(ferrocenyl)ethynyl)-copper-tri-gold hexafluorophosphate dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 937898: Experimental Crystal Structure Determination

2013

Related Article: Thuy Minh Dau, Julia R. Shakirova, Antonio Doménech, Janne Jänis, Matti Haukka, Elena V. Grachova, Tapani A. Pakkanen, Sergey P. Tunik, Igor O. Koshevoy|2013|Eur.J.Inorg.Chem.||4976|doi:10.1002/ejic.201300615

Space GroupCrystallographyCrystal Systembis(mu~3~-bis((Diphenylphosphino)methyl)phenylphosphine)-bis((ferrocenyl)ethynyl)-tetra-gold bis(hexafluorophosphate) acetone unknown solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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