0000000001309957
AUTHOR
Danielle Cangussu De Castro Gomes
A giant hybrid organic-inorganic octahedron from a narrow rim carboxylate calixarene.
Here we discovered an unprecedented giant octahedral coordination compound bearing 16 Zn2+, 12 Na+, 8 O2-, 4 OH-, 13 H2O and 6 L4- ligands [L4- = fully deprotonated tetra(carboxymethoxy)calix[4]arene]. Its structure was elucidated by single-crystal X-ray diffraction, wavelength-dispersive X-ray spectroscopy and MALDI-TOF mass spectrometry. This compound, Zn8Na6L6⊃Zn8Na6O8(OH)4(H2O)13 (external⊃internal), has eight tetrahedral zinc ions forming the coordination vertices of an outermost cube where carboxylate groups from the sodium calixarenes are anchored. Its core consists of eight Zn2+, six Na+, eight O2-, and four OH- distributed over three layers, besides thirteen coordinated H2O molecul…
Syntheses, crystal structures and magnetic properties of tricyanomethanide-containing bis(2-pyrimidylcarbonyl)amidate copper(II) complexes
Abstract Three new copper(II) complexes of formulae [Cu(bpcam)(tcm)(H2O)] · 2H2O (1), [Cu(bpcam)(tcm)(H2O)] (2) and [Cu(bpcam)(tcm)]n (3) [bpcam = bis(2-pyrimidylcarbonyl)amidate and tcm = tricyanomethanide] have been prepared and their structures determined by single crystal X-ray diffraction. Complexes 1 and 2 are mononuclear species where each copper atom is five-coordinated in a somewhat distorted square pyramidal environment with a tridentate bpcam ligand and a terminally bound tcm group building the basal plane and a water molecule in the apical position. Compound 3 is a uniform copper(II) chain where the [Cu(bpcam)]+ units are connected through single μ-1,5-tcm bridges which link one…
Syntheses, crystal structures and magnetic properties of mono- and polynuclear [bis(2-arylcarbonyl)amidate]copper(II) complexes
Abstract Five copper(II) complexes of formulas [Cu(bpcam)(CN)(H2O)] (1), [Cu(bpcam)(N3)(H2O)]2 (2), [Cu(bpcam)(NCS)(H2O)] (3), [Cu(bpcam)(dca)(H2O)]2 (4) and [Cu(bpca)(tcm)]n (5) [bpcam = bis(2-pyrimidylcarbonyl)amidate, bpca = bis(2-pyridylcarbonyl)amidate, dca = dicyanamide and tcm = tricyanomethanide] have been prepared and their structures determined by single crystal X-ray diffraction. Compounds 1 and 3 are mononuclear species where each copper atom is five coordinated with a tridentate bpcam and a terminally bound cyanide (1)/thiocyanate (3) ligands creating a basal plane with a water molecule in the axial position of a distorted square pyramid. Compound 2 is made of neutral di-μ-1,1-…
Copper(II)-assisted hydrolysis of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (tpymt): syntheses, crystal structures and magnetic properties of [Cu(bpcam)(H2O)2]ClO4·3H2O, [Cu(bpcam)(H2O)2][Cu(bpcam)(H2O)(SO4)]·2H2O and [Cu2(bpcam)2(H2O)2(SO4)]·H2O [bpcam=bis(2-pyrimidylcarbonyl)amidate]
Abstract The reaction of the 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (tpymt) ligand with copper(II) perchlorate or sulfate in aqueous solution affords complexes [Cu(bpcam)(H2O)2]ClO4 · 3H2O (1), [Cu(bpcam)(H2O)2][Cu(bpcam)(H2O)(SO4)] · 2H2O (2) and [Cu2(bpcam)2(H2O)2(SO4)] · H2O (3) [bpcam = bis(2-pyrimidylcarbonyl)amidate], whose structures have been determined by single-crystal X-ray diffraction studies. Copper(II) promotes the hydrolysis of tpymt in mild conditions yielding the bpcam group which is present in the structures of 1–3 as a tridentate ligand. The structure of 1 consists of mononuclear [Cu(bpcam)(H2O)2]+ cations, uncoordinated perchlorate anions and water of crystallization. Th…
CCDC 1876681: Experimental Crystal Structure Determination
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CCDC 2000511: Experimental Crystal Structure Determination
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CCDC 1859264: Experimental Crystal Structure Determination
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CCDC 2000512: Experimental Crystal Structure Determination
Related Article: Fernando Machado dos Santos, Meiry Edivirges Alvarenga, Ana Karoline Silva Mendanha Valdo, Renato Rabelo, Danielle Cangussu de Castro Gomes, Ângelo de Fátima, Thiago Vinicius Costa Lara, Cleiton Moreira da Silva, Thiago Teixeira Tasso, João Honorato Araujo Neto, Alzir Azevedo Batista, Alejandro Pedro Ayala, Javier Alcides Ellena, Vinicius Ferraz Guimarães, Cecília Maria Alves Oliveira, Lidya Cardozo da Silva, Boniek Gontijo Vaz, Felipe Terra Martins|2020|Chem.Commun.|56|15024|doi:10.1039/D0CC07043B