0000000001310298

AUTHOR

Lapo Bogani

showing 4 related works from this author

Custom coordination environments for lanthanoids: tripodal ligands achieve near-perfect octahedral coordination for two dysprosium-based molecular na…

2017

Controlling the coordination sphere of lanthanoid complexes is a challenging critical step toward controlling their relaxation properties. Here we present the synthesis of hexacoordinated dysprosium single-molecule magnets, where tripodal ligands achieve a near-perfect octahedral coordination. We perform a complete experimental and theoretical investigation of their magnetic properties, including a full single-crystal magnetic anisotropy analysis. The combination of electrostatic and crystal-field computational tools (SIMPRE and CONDON codes) allows us to explain the static behavior of these systems in detail. NRF-2015R1A2A1A10055658 Grant NRF-2012-0008901 NRF2010-0020209 ERC-CoG-647301 DEC…

LanthanideCoordination sphere010405 organic chemistryUNESCO::QUÍMICARelaxation (NMR)chemistry.chemical_element010402 general chemistry01 natural sciences:QUÍMICA [UNESCO]0104 chemical sciencesInorganic ChemistryMagnetic anisotropychemistryOctahedronComputational chemistryChemical physicsMagnetDysprosiumPhysical and Theoretical ChemistryCoordination geometry
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Magneto-optical Investigations of Nanostructured Materials Based on Single Molecule Magnets Monitor Strong Environmental Effects

2007

The determination of the magnetic properties of molecular magnets in environments similar to those used in spintronic devices is fundamental for the development of applications. Single-molecule magnets (SMMs) are molecular cluster systems that display magnetic hysteresis of dynamical origin at low temperature. As they behave like perfectly monodisperse nanomagnets and show clear macroscopic quantum effects in their magnetic properties, they are extremely appealing candidates for the forthcoming generation of molecular devices: they have been proposed as efficient systems for quantum computation, ultra-high-density magnetic recording media, and molecular spintronic systems. These attractive …

Materials scienceMagnetismOPTICAL MODESMN12O12(O2CR)(16)(H2O)(4)GOLD SURFACESRELAXATIONNanotechnologySURFACE PHONONSMN-12 NANOMAGNETSCluster (physics)General Materials ScienceThin filmLangmuir-Blodgett filmsSpintronicsMechanical EngineeringMagnetic hysteresisNanomagnetmagnetic hysteresisAmorphous solidIONIC CRYSTAL SLABMESOPOROUS SILICAMagnetic coreMechanics of MaterialsChemical physicsmagnetismcluster compoundsCLUSTERSQUANTUMIONIC CRYSTAL SLAB; MESOPOROUS SILICA; MN-12 NANOMAGNETS; SURFACE PHONONS; OPTICAL MODES; GOLD SURFACES; QUANTUM; MN12O12(O2CR)(16)(H2O)(4); RELAXATION; CLUSTERSLangmuir-Blodgett films; magnetic hysteresis; magnetism; cluster compounds
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CCDC 904371: Experimental Crystal Structure Determination

2016

Related Article: Kwang Soo Lim, Shang-Da Jiang, Bong Ho Koo, Dae Won Ryu, Woo Ram Lee, Eui Kwan Koh, José J. Baldoví, Alejandro Gaita-Ariño, Eugenio Coronado, Michael Slota, Lapo Bogani and Chang Seop Hong|2016|CSD Communication|||

Space GroupCrystallographyhexakis(mu-di-isopropoxy(oxo)phosphanyl)-bis(eta5-cyclopentadienyl)-di-cobalt(iii)-dysprosium(iii) hexafluorophosphateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 904370: Experimental Crystal Structure Determination

2016

Related Article: Kwang Soo Lim, Shang-Da Jiang, Bong Ho Koo, Dae Won Ryu, Woo Ram Lee, Eui Kwan Koh, José J. Baldoví, Alejandro Gaita-Ariño, Eugenio Coronado, Michael Slota, Lapo Bogani and Chang Seop Hong|2016|CSD Communication|||

Space GroupCrystallographyhexakis(mu-diethoxy(oxo)phosphanyl)-bis(eta5-cyclopentadienyl)-di-cobalt(iii)-dysprosium(iii) hexafluorophosphateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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