Author: Cristian Martínez Hernández

0000000001310313

AUTHOR

Cristian Martínez Hernández

Solvent-modulation of the structure and dimensionality in lanthanoid-anilato coordination polymers.

We show the key role that the size and shape of the solvent molecules may play in the dimensionality and structure of a series of lanthanoid–chloranilato coordination polymers. We report the synthesis, structure and magnetic properties of six different coordination polymers prepared with Er(III) and chloranilato (C6O4Cl22− = 3,6-dichloro-2,5-dihydroxy-1,4-benzoquinone) and six different solvents: [Er2(C6O4Cl2)3(H2O)6]·10H2O (1), [Er2(C6O4Cl2)3(FMA)6]·4FMA·2H2O (2) (FMA = formamide = NH2CHO), [Er2(C6O4Cl2)3(DMSO)4]·2DMSO·2H2O (3) (DMSO = dimethy sulfoxide = Me2SO), [Er2(C6O4Cl2)3(DMF)6] (4) (DMF = dimethylformamide = Me2NCHO), [Er2(C6O4Cl2)3(DMA)4] (5) (DMA = dimethylacetamide = Me2NC(Me)O) …

research product

Sensores magnéticos basados en polímeros de coordinación porosos con ordenamiento magnético

La Tesis que aquí se presenta tiene como objetivo principal el diseño y estudio de las propiedades de una gran serie de compuestos que actúan como imanes moleculares. Estos compuestos consisten en polímeros de coordinación basados en el ligando anilato (C6O4X22-, siendo X = Cl o Br) con metales de transición como centros metálicos responsables del comportamiento magnético de dichos materiales. Así pues, en el Capítulo 1 se presenta una familia de compuestos isoestructurales entre sí con capas aniónicas en forma de panal abeja que se superponen de modo eclipsado originando canales hexagonales. En el interior de los canales hexagonales se alojan moléculas de disolvente que tienen un papel fun…

research product

CCDC 1586538: Experimental Crystal Structure Determination

Related Article: Samia Benmansour, Irene Pérez-Herráez, Christian Cerezo-Navarrete, Gustavo López-Martínez, Cristian Martínez Hernández, Carlos J. Gómez-García|2018|Dalton Trans.|47|6729|doi:10.1039/C8DT00143J

research product

CCDC 1586535: Experimental Crystal Structure Determination

Related Article: Samia Benmansour, Irene Pérez-Herráez, Christian Cerezo-Navarrete, Gustavo López-Martínez, Cristian Martínez Hernández, Carlos J. Gómez-García|2018|Dalton Trans.|47|6729|doi:10.1039/C8DT00143J

research product

CCDC 1586536: Experimental Crystal Structure Determination

Related Article: Samia Benmansour, Irene Pérez-Herráez, Christian Cerezo-Navarrete, Gustavo López-Martínez, Cristian Martínez Hernández, Carlos J. Gómez-García|2018|Dalton Trans.|47|6729|doi:10.1039/C8DT00143J

research product

CCDC 1586540: Experimental Crystal Structure Determination

Related Article: Samia Benmansour, Irene Pérez-Herráez, Christian Cerezo-Navarrete, Gustavo López-Martínez, Cristian Martínez Hernández, Carlos J. Gómez-García|2018|Dalton Trans.|47|6729|doi:10.1039/C8DT00143J

research product

CCDC 1944125: Experimental Crystal Structure Determination

Related Article: Samia Benmansour, Irene Pérez-Herráez, Christian Cerezo-Navarrete, Gustavo López-Martínez, Cristian Martínez Hernández, Carlos J. Gómez-García|2018|Dalton Trans.|47|6729|doi:10.1039/C8DT00143J

research product

CCDC 1586539: Experimental Crystal Structure Determination

Related Article: Samia Benmansour, Irene Pérez-Herráez, Christian Cerezo-Navarrete, Gustavo López-Martínez, Cristian Martínez Hernández, Carlos J. Gómez-García|2018|Dalton Trans.|47|6729|doi:10.1039/C8DT00143J

research product

CCDC 1586537: Experimental Crystal Structure Determination

Related Article: Samia Benmansour, Irene Pérez-Herráez, Christian Cerezo-Navarrete, Gustavo López-Martínez, Cristian Martínez Hernández, Carlos J. Gómez-García|2018|Dalton Trans.|47|6729|doi:10.1039/C8DT00143J

research product

PEPhysical Sciences and Engineering
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