Author: Thomas Devic

0000000001310319

AUTHOR

Thomas Devic

showing 3 related works from this author

A tris-oxovanadium pyrogallate complex: synthesis, structure, and magnetic and electronic properties

2021

International audience; With the aim of identifying new cation-phenolate complexes, we herein investigated the reactivity of pyrogallol (H(3)pgal) with vanadium salts. A trimetallic anionic complex was identified, and found to be formed under a broad set of reaction conditions. This complex, with the formula V3O3(pgal)(3)(3-), consists of three oxovanadium(iv) units connected together by three pyrogallate ligands to afford a bowl-shaped species presenting a pseudo 3-fold symmetry axis. Its crystal structure is reported, as well as its characterisation by a broad set of techniques, including powder X-ray diffraction, thermogravimetric analysis, infrared and Raman spectroscopy, and solid stat…

Thermogravimetric analysisMaterials science010405 organic chemistryInfraredQuímica organometàl·licaVanadiumchemistry.chemical_elementCrystal structure010402 general chemistry01 natural sciences0104 chemical sciencesInorganic ChemistryCompostos orgànics Síntesisymbols.namesakeCrystallographychemistry[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]symbolsMetal-organic frameworkReactivity (chemistry)Diffuse reflectionRaman spectroscopyDalton Transactions

researchProduct

CCDC 2087735: Experimental Crystal Structure Determination

2021

Related Article: Hassan Mkhadder, Morgane Denis, Mónica Giménez-Marqués, Walter Cañón-Mancisidor, Bernard Humbert, Elise Deunf, Philippe Poizot, Thomas Devic|2021|Dalton Trans.|50|13399|doi:10.1039/D1DT01990B

Space GroupCrystallographyCrystal SystemCrystal Structuretri-potassium tris(mu-benzene-123-triolato)-tris(oxido)-tri-vanadium NN-dimethylformamide solvateCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 2087736: Experimental Crystal Structure Determination

2021

Related Article: Hassan Mkhadder, Morgane Denis, Mónica Giménez-Marqués, Walter Cañón-Mancisidor, Bernard Humbert, Elise Deunf, Philippe Poizot, Thomas Devic|2021|Dalton Trans.|50|13399|doi:10.1039/D1DT01990B

Space GroupCrystallographyCrystal Systemtri-potassium tris(mu-benzene-123-triolato)-tris(oxido)-tri-vanadium tetrahydrateCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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