0000000001310320

AUTHOR

Irina A. Boyarskaya

showing 11 related works from this author

Syntheses and Structures of a Series of Acyclic Diaminocarbene Palladium(II) Complexes Derived from 3,4-Diaryl-1H-pyrrol-2,5-diimines and Bisisocyani…

2018

Reactions of 3,4-diaryl-1H-pyrrol-2,5-diimines with various bisisocyanide palladium(II) complexes were studied. The coupling proceeds with one isocyanide ligand to accomplish the acyclic diaminocarbene complexes. The structure of generated diaminocarbene complexes depends on bulkiness of isocyanide ligand in the bisisocyanide complexes of palladium(II). The imino-group of 3,4-diaryl-1H-pyrrol-2,5-diimine reacts with one isocyanide ligand of cis-[PdCl2(CN–R)2] (R = i-Pr, Cy, t-Bu, Bn), and the nitrogen atom of the pyrrole ring is coordinated to the palladium center as the second isocyanide ligand remains intact. In the case of cis-[PdCl2(CN–R)2] (R = 2-acyloxyphenyl, 2-sulfonyloxyphenyl), on…

Coordination sphere010405 organic chemistryChemistryLigandIsocyanideOrganic Chemistrychemistry.chemical_elementMolecular spectroscopy010402 general chemistryRing (chemistry)01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundPolymer chemistryPhysical and Theoretical ChemistryCyclic voltammetryPyrrolePalladiumOrganometallics
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Triple associates based on (oxime)Pt(II) species, 18-crown-6, and water: Synthesis, structural characterization, and DFT study

2014

Abstract The associates 2(cis-[PtCl2(acetoxime)2])⋅18-crown-6⋅2H2O (1), 2(cis-[PtBr2(acetoxime)2])⋅18-crown-6⋅2H2O (2), and trans-[PtCl2(acetaldoxime)2]⋅(18-crown-6)⋅2H2O (3) were synthesized by co-crystallization of free corresponding platinum species and 18-crown-6 from wet solvents and characterized by 1H NMR and IR spectroscopies, high-resolution mass-spectrometry (ESI), TG/DTA, and X-ray crystallography. The (oxime)Pt(II) species are assembled with 18-crown-6 and water by hydrogen bonding between the hydroxylic hydrogen atoms of the oxime ligands and the oxygen atom of water and between the hydrogen atoms of water and the oxygen atoms of 18-crown-6. In 2(cis-[PtX2(acetoxime)2])⋅18-crow…

chemistry.chemical_classificationHydrogen bondOrganic ChemistryInorganic chemistry18-Crown-6chemistry.chemical_elementOximeAnalytical ChemistryInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryProton NMRMoleculeAcetaldoximePlatinumta116SpectroscopyCrown etherJournal of Molecular Structure
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C,N-chelated diaminocarbene platinum(II) complexes derived from 3,4-diaryl-1H-pyrrol-2,5-diimines and cis-dichlorobis(isonitrile)platinum(II): Synthe…

2020

The reaction of 3,4-diaryl-1H-pyrrol-2,5-diimines with cis-dichlorobis(isonitrile)platinum(II) affords the C,N-chelated diaminocarbene platinum(II) complexes, which have been fully characterized including molecular spectroscopy, single crystal X-ray diffraction and DFT calculations. The obtained platinum(II) complexes are effective catalysts for the hydrosilylation of alkynes and alkenes. Thus, the reaction of phenylacetylene with triethoxysilane leads to the formation of α- and β-(E)-vinylsilanes, generating TON's in the range of 103 to 104 and TOF's in the range of 102 to 103 h−1. Also, the cross-linked silicones, possessing the luminescence properties, were obtained by the hydrosilylatio…

LuminescenceHydrosilylationchemistry.chemical_element010402 general chemistry01 natural sciencesBiochemistryCatalysisCatalysisInorganic Chemistrychemistry.chemical_compoundAnti-cancer activityPolymer chemistryluminescenceMaterials ChemistryChelationPhysical and Theoretical Chemistrydiaminocarbene platinum(II) complexescatalysis010405 organic chemistryOrganic Chemistryhydrosilylation0104 chemical scienceschemistryPhenylacetyleneDiaminocarbene platinum(II) complexesHydrosilylationTriethoxysilaneanti-cancer activityLuminescencePlatinumSingle crystalJournal of Organometallic Chemistry
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CCDC 1983029: Experimental Crystal Structure Determination

2020

Related Article: Anastasiia M. Afanasenko, Tatiana G. Chulkova, Irina A. Boyarskaya, Regina M. Islamova, Anton A. Legin, Bernhard K. Keppler, Stanislav I. Selivanov, Anatoly N. Vereshchagin, Michail N. Elinson, Matti Haukka|2020|J.Organomet.Chem.|923|121435|doi:10.1016/j.jorganchem.2020.121435

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters[{[5-iminio-34-bis(4-methylphenyl)pyrrol-1-id-2(5H)-ylidene]amino}(cyclohexyliminio)methyl]-chloro-[cyclohexylisocyano]-platinum chloride dichloromethane solvateExperimental 3D Coordinates
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CCDC 880417: Experimental Crystal Structure Determination

2014

Related Article: Evgeny Yu. Bulatov, Tatiana G. Chulkova, Irina A. Boyarskaya, Veniamin V. Kondratiev, Matti Haukka, Vadim Yu. Kukushkin|2014|J.Mol.Struct.|1068|176|doi:10.1016/j.molstruc.2014.04.010

Space GroupCrystallographyCrystal SystemCrystal Structurebis(dibromo-bis(N-hydroxypropan-2-imine)-platinum) 147101316-hexaoxacyclooctadecane dihydrateCell ParametersExperimental 3D Coordinates
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CCDC 868793: Experimental Crystal Structure Determination

2014

Related Article: Evgeny Yu. Bulatov, Tatiana G. Chulkova, Irina A. Boyarskaya, Veniamin V. Kondratiev, Matti Haukka, Vadim Yu. Kukushkin|2014|J.Mol.Struct.|1068|176|doi:10.1016/j.molstruc.2014.04.010

dichloro-bis(N-hydroxyethanimine)-platinum(ii) 147101316-hexaoxacyclooctadecane dihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 880416: Experimental Crystal Structure Determination

2014

Related Article: Evgeny Yu. Bulatov, Tatiana G. Chulkova, Irina A. Boyarskaya, Veniamin V. Kondratiev, Matti Haukka, Vadim Yu. Kukushkin|2014|J.Mol.Struct.|1068|176|doi:10.1016/j.molstruc.2014.04.010

Space GroupCrystallographyCrystal SystemCrystal Structurebis(dichloro-bis(N-hydroxypropan-2-imine)-platinum) 147101316-hexaoxacyclooctadecane dihydrateCell ParametersExperimental 3D Coordinates
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CCDC 1817631: Experimental Crystal Structure Determination

2018

Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725

Space GroupCrystallography(mu-chloro)-(mu-2-azanidylidene-34-bis(4-methoxyphenyl)-5-((((propan-2-yl)imino)methyl)imino)-25-dihydropyrrolyl)-(2-iminio-34-bis(4-methoxyphenyl)-5-((((propan-2-yl)imino)methyl)imino)-25-dihydropyrrolyl)-chloro-di-palladiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1818370: Experimental Crystal Structure Determination

2018

Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-{[(t-butylimino)methanidyl]imino}-5-iminio-34-diphenyl-25-dihydropyrrol-1-yl)-chloro-(2-isocyano-2-methylpropane)-palladium chloride dichloromethane solvateExperimental 3D Coordinates
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CCDC 1817212: Experimental Crystal Structure Determination

2018

Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-cyano)-({[5-amino-34-bis(4-methylphenyl)-2H-pyrrol-2-ylidene]amino}(t-butylamino)methylidene)-({[5-amino-34-bis(4-methylphenyl)pyrrol-1-id-2-yl]amino}(t-butylamino)methylidene)-dichloro-di-palladium(ii) dichloromethane solvate monohydrateExperimental 3D Coordinates
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CCDC 1822187: Experimental Crystal Structure Determination

2018

Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-iminio-5-{[({5-methyl-2-[(4-methylbenzene-1-sulfonyl)oxy]phenyl}imino)methanidyl]imino}-34-diphenyl-25-dihydropyrrol-1-yl)-bis(chloro)-palladium acetonitrile solvateExperimental 3D Coordinates
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