Author: Wenjian Zhang

0000000001310639

AUTHOR

Wenjian Zhang

Synthesis and structural characterisation of germanium(II) halide complexes with neutral N-donor ligands.

The Ge(II) complexes [GeX(2)(L-L)] (L-L = 1,10-phen (X = Cl, Br); L-L = Me(2)N(CH(2))(2)NMe(2), 2,2'-bipy (X = Cl)), [GeX(L-L)][GeX(3)] (L-L = 2,2'-bipy (X = Br); L-L = pmdta (MeN(CH(2)CH(2)NMe(2))(2)) (X = Cl, Br)) have been prepared and their crystal structures determined. The crystal structure of [GeCl(2){Me(2)N(CH(2))(2)NMe(2)}] shows a weakly associated centrosymmetric dimer based upon distorted square-pyramidal coordination at Ge(II) and containing asymmetrically chelating diamine ligands. The structure of [GeCl(2)(2,2'-bipy)] contains a chelating 2,2'-bipy ligand and forms a zig-zag chain polymer via long-range intermolecular Ge...Cl bridging interactions, leading to a very distorted…

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CCDC 724642: Experimental Crystal Structure Determination

Related Article: Fei Cheng, J.M.Dyke, F.Ferrante, A.L.Hector, W.Levason, G.Reid, M.Webster, Wenjian Zhang|2010|Dalton Trans.|39|847|doi:10.1039/b911016j

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CCDC 724632: Experimental Crystal Structure Determination

Related Article: Fei Cheng, J.M.Dyke, F.Ferrante, A.L.Hector, W.Levason, G.Reid, M.Webster, Wenjian Zhang|2010|Dalton Trans.|39|847|doi:10.1039/b911016j

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CCDC 724631: Experimental Crystal Structure Determination

Related Article: Fei Cheng, J.M.Dyke, F.Ferrante, A.L.Hector, W.Levason, G.Reid, M.Webster, Wenjian Zhang|2010|Dalton Trans.|39|847|doi:10.1039/b911016j

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CCDC 724634: Experimental Crystal Structure Determination

Related Article: Fei Cheng, J.M.Dyke, F.Ferrante, A.L.Hector, W.Levason, G.Reid, M.Webster, Wenjian Zhang|2010|Dalton Trans.|39|847|doi:10.1039/b911016j

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CCDC 724636: Experimental Crystal Structure Determination

Related Article: Fei Cheng, J.M.Dyke, F.Ferrante, A.L.Hector, W.Levason, G.Reid, M.Webster, Wenjian Zhang|2010|Dalton Trans.|39|847|doi:10.1039/b911016j

research product

CCDC 724633: Experimental Crystal Structure Determination

Related Article: Fei Cheng, J.M.Dyke, F.Ferrante, A.L.Hector, W.Levason, G.Reid, M.Webster, Wenjian Zhang|2010|Dalton Trans.|39|847|doi:10.1039/b911016j

research product

CCDC 724635: Experimental Crystal Structure Determination

Related Article: Fei Cheng, J.M.Dyke, F.Ferrante, A.L.Hector, W.Levason, G.Reid, M.Webster, Wenjian Zhang|2010|Dalton Trans.|39|847|doi:10.1039/b911016j

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