0000000001310775

AUTHOR

A. Garcia-raso

showing 5 related works from this author

Unsaturated carboxylic acid dienolates. Addition to substituted cyclohexanones. Inverted kinetic and thermodynamic stereoselectivities.

1987

Abstract Addition of the lithium dienolate derived from crotonic acid to monosubstituted cyclohexanones occurs through the α and γ carbon atoms of the dienolate in the cold and on heating, respectively. For any regioselectivity, equatorial approach is found under kinetic conditions, but equilibration favours products from axial attack and selectivity may be inverted.

chemistry.chemical_classificationAddition reactionKetoneCarboxylic acidOrganic Chemistrychemistry.chemical_elementRegioselectivityBiochemistryMedicinal chemistrychemistryDrug DiscoveryOrganic chemistryLithiumStereoselectivityAliphatic compoundSelectivityTetrahedron Letters
researchProduct

Impact of sex, age, and risk factors for venous thromboembolism on the initial presentation of first isolated symptomatic acute deep vein thrombosis

2019

Abstract Background and aims Sex-specific differences exist for the initial presentation of acute venous thromboembolism (VTE): men are more likely to present with proximal deep vein thrombosis (DVT) in the lower limbs (versus pulmonary embolism [PE] or isolated distal DVT [IDDVT]) than women. We studied in detail the influence of sex, age, and VTE risk factors on the initial presentation of IDDVT versus proximal DVT. Methods A total of 24,911 patients with a first episode of objectively diagnosed acute symptomatic lower-limb DVT (without symptomatic PE) were enrolled in RIETE (years 2000–2017) and included in the present analysis. Results A total of 4266 (17.1%) patients had IDDVT. No tren…

medicine.medical_specialtyEpidemiologyDeep vein030204 cardiovascular system & hematologyDistal DVT03 medical and health sciences0302 clinical medicineDeep vein thrombosiDeep vein thrombosisInternal medicineEpidemiologymedicinecardiovascular diseasesFirst episodePregnancyProvoking risk factorsbusiness.industryCancerHematologymedicine.diseaseThrombosisPathophysiologyPulmonary embolismmedicine.anatomical_structureProvoking risk factor030220 oncology & carcinogenesisSexbusinessVenous thromboembolism
researchProduct

CCDC 137960: Experimental Crystal Structure Determination

2000

Related Article: A.Garcia-Raso, J.J.Fiol, S.Rigo, A.Lopez-Lopez, E.Molins, E.Espinosa, E.Borras, G.Alzuet, J.Borras, A.Castineiras|2000|Polyhedron|19|991|doi:10.1016/S0277-5387(00)00355-7

Space GroupCrystallographyCrystal SystemDiaqua-dipyridyl-bis(sulfamethoxazolato)-zinc(ii) dihydrateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 137959: Experimental Crystal Structure Determination

2000

Related Article: A.Garcia-Raso, J.J.Fiol, S.Rigo, A.Lopez-Lopez, E.Molins, E.Espinosa, E.Borras, G.Alzuet, J.Borras, A.Castineiras|2000|Polyhedron|19|991|doi:10.1016/S0277-5387(00)00355-7

Space GroupCrystallographycatena-(Aqua-bis(mu~2~-sulfadimidinato)-cadmium(ii) dihydrate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 137958: Experimental Crystal Structure Determination

2000

Related Article: A.Garcia-Raso, J.J.Fiol, S.Rigo, A.Lopez-Lopez, E.Molins, E.Espinosa, E.Borras, G.Alzuet, J.Borras, A.Castineiras|2000|Polyhedron|19|991|doi:10.1016/S0277-5387(00)00355-7

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(sulfamethoxypyridazinato)-mercury(ii)Experimental 3D Coordinates
researchProduct