0000000001310865
AUTHOR
Jiye Wang
Dinuclear chloroneodymium quinolinylcarboxylates: The molecular structures affected by water and the catalytic behavior toward isoprene polymerization
Abstract A series of dinuclear chloroneodymium quinolinylcarboxylate compounds was synthesized and characterized. The nature and importance of metal-organic aggregations have been considered as an important factor regarding the molecular structure and catalytic performance. The neodymium center in all the title compounds exhibits the coordination numbers of 8. Cage aggregation was observed in the solid state, and the cyclic arrangement was achieved when water molecules were incorporated into the structure. Upon the activation with Al(i-Bu)3, all the title neodymium compounds form the efficient catalysts for isoprene polymerization. The catalytic activities are not strongly affected by the m…
CCDC 1486040: Experimental Crystal Structure Determination
Related Article: Wenjuan Zhang, Lin Qian, Lixia He, Yongqiang Qian, Jiye Wang, Zhonghua Wang, Qingju Lin, Xiang Hao, Zygmunt Flisak, Wen-Hua Sun|2016|Inorg.Chim.Acta|453|589|doi:10.1016/j.ica.2016.09.030
CCDC 1486038: Experimental Crystal Structure Determination
Related Article: Wenjuan Zhang, Lin Qian, Lixia He, Yongqiang Qian, Jiye Wang, Zhonghua Wang, Qingju Lin, Xiang Hao, Zygmunt Flisak, Wen-Hua Sun|2016|Inorg.Chim.Acta|453|589|doi:10.1016/j.ica.2016.09.030
CCDC 1486039: Experimental Crystal Structure Determination
Related Article: Wenjuan Zhang, Lin Qian, Lixia He, Yongqiang Qian, Jiye Wang, Zhonghua Wang, Qingju Lin, Xiang Hao, Zygmunt Flisak, Wen-Hua Sun|2016|Inorg.Chim.Acta|453|589|doi:10.1016/j.ica.2016.09.030