0000000001310899

AUTHOR

Stefano Libri

showing 6 related works from this author

Coordination polymer flexibility leads to polymorphism and enables a crystalline solid-vapour reaction: a multi-technique mechanistic study.

2015

Despite an absence of conventional porosity, the 1D coordination polymer [Ag4 (O2 C(CF2 )2 CF3 )4 (TMP)3 ] (1; TMP=tetramethylpyrazine) can absorb small alcohols from the vapour phase, which insert into AgO bonds to yield coordination polymers [Ag4 (O2 C(CF2 )2 CF3 )4 (TMP)3 (ROH)2 ] (1-ROH; R=Me, Et, iPr). The reactions are reversible single-crystal-to-single-crystal transformations. Vapour-solid equilibria have been examined by gas-phase IR spectroscopy (K=5.68(9)×10(-5) (MeOH), 9.5(3)×10(-6) (EtOH), 6.14(5)×10(-5) (iPrOH) at 295 K, 1 bar). Thermal analyses (TGA, DSC) have enabled quantitative comparison of two-step reactions 1-ROH→1→2, in which 2 is the 2D coordination polymer [Ag4 (O2 …

In situporosityin situ diffractionCoordination polymerStereochemistrygas-phase spectroscopyInfrared spectroscopyCatalysislaw.inventionpolymorphismchemistry.chemical_compoundOptical microscopelawQDThermal analysisTP155chemistry.chemical_classificationChemistryOrganic ChemistryGeneral ChemistryPolymerCoordination PolymersFull PapersCrystallographyPolymorphism (materials science)microscopysolid-state reactionsPowder diffractionthermal analysisChemistry (Weinheim an der Bergstrasse, Germany)
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One-dimensional organization of free radicals via halogen bonding

2012

Halogen bonds have been applied for the supramolecular organization of organic free radicals in the solid state and their role in the propagation of the magnetic exchange has been studied.

Halogen bondChemistryRadicalInorganic chemistryHalogenPolymer chemistrySolid-stateSupramolecular chemistryGeneral Materials ScienceGeneral ChemistryCondensed Matter PhysicsMagnetic exchangeCrystEngComm
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CCDC 1044598: Experimental Crystal Structure Determination

2015

Related Article: Iñigo J. Vitórica-Yrezábal, Stefano Libri, Jason R. Loader, Guillermo Mínguez Espallargas, Michael Hippler, Ashleigh J. Fletcher, Stephen P. Thompson, John E. Warren, Daniele Musumeci, Michael D. Ward, Lee Brammer|2015|Chem.-Eur.J.|21|8799|doi:10.1002/chem.201500514

Space GroupCrystallographycatena-((mu2-Tetramethylpyrazine)-(heptafluorobutanoato-OO')-silver(i))Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1044595: Experimental Crystal Structure Determination

2015

Related Article: Iñigo J. Vitórica-Yrezábal, Stefano Libri, Jason R. Loader, Guillermo Mínguez Espallargas, Michael Hippler, Ashleigh J. Fletcher, Stephen P. Thompson, John E. Warren, Daniele Musumeci, Michael D. Ward, Lee Brammer|2015|Chem.-Eur.J.|21|8799|doi:10.1002/chem.201500514

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tetrakis(mu2-Heptafluorobutanoato)-tris(mu2-tetramethylpyrazine)-tetra-silver)Experimental 3D Coordinates
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CCDC 1044597: Experimental Crystal Structure Determination

2015

Related Article: Iñigo J. Vitórica-Yrezábal, Stefano Libri, Jason R. Loader, Guillermo Mínguez Espallargas, Michael Hippler, Ashleigh J. Fletcher, Stephen P. Thompson, John E. Warren, Daniele Musumeci, Michael D. Ward, Lee Brammer|2015|Chem.-Eur.J.|21|8799|doi:10.1002/chem.201500514

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tetrakis(mu2-Heptafluorobutanoato)-tris(mu2-tetramethylpyrazine)-tetra-silver)Experimental 3D Coordinates
researchProduct

CCDC 1044596: Experimental Crystal Structure Determination

2015

Related Article: Iñigo J. Vitórica-Yrezábal, Stefano Libri, Jason R. Loader, Guillermo Mínguez Espallargas, Michael Hippler, Ashleigh J. Fletcher, Stephen P. Thompson, John E. Warren, Daniele Musumeci, Michael D. Ward, Lee Brammer|2015|Chem.-Eur.J.|21|8799|doi:10.1002/chem.201500514

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tetrakis(mu2-Heptafluorobutanoato)-tris(mu2-tetramethylpyrazine)-tetra-silver)Experimental 3D Coordinates
researchProduct