0000000001311225

AUTHOR

Liliana Cseh

showing 7 related works from this author

Polynuclear copper(II) complexes with hexadentate Schiff base directed by the counter ion. Syntheses, crystal structures and magnetic properties

2018

Abstract Four new complexes, [Cu 9 L 6 ( µ 3 -ClO 4 ) 2 ](ClO 4 ) 4 ·4CHCl 3 1 , [Cu 3 L 2 (H 2 O) 2 ](ClO 4 ) 2 ·3H 2 O 2 , [Cu 6 L 4 (N 3 ) 2 ](ClO 4 ) 2 3 and [Cu 2 L(CH 3 COO) 2 ] 4 , where H 2 L stands for the Schiff base N , N ′-bis[(2-hydroxybenzilideneamino)-propyl]-piperazine, were obtained and structurally characterized. Compounds 1 , 2 and 3 contain the Cu 3 L 2 2+ entities in which L 2− acts in an unsymmetrical mode with N 3 O donor set wrapped around marginal copper(II) and with the remained NO sets bound to the central copper ion. The marginal copper(II) ions are in distorted square pyramidal environment, whereas that of the central one is square planar. In 1 , the peripheral …

Schiff base010405 organic chemistryChemistryLigandStereochemistryMetal ions in aqueous solutionchemistry.chemical_elementCrystal structure010402 general chemistry01 natural sciencesCopperSquare pyramidal molecular geometry0104 chemical sciencesInorganic ChemistryCrystallographychemistry.chemical_compoundPerchlorateMaterials ChemistryMoleculePhysical and Theoretical ChemistryInorganica Chimica Acta
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Chemistry and Photochemistry of 2,6-Bis(2-hydroxybenzilidene)cyclohexanone. An Example of a Compound Following the Anthocyanins Network of Chemical R…

2014

The kinetics and thermodynamics of the 2,6-bis(2-hydroxybenzilidene)cyclohexanone chemical reactions network was studied at different pH values using NMR, UV-vis, continuous irradiation, and flash photolysis. The chemical behavior of the system partially resembles anthocyanins and their analogue compounds. 2,6-Bis(2-hydroxybenzilidene)cyclohexanone exhibits a slow color change from yellow to red styrylflavylium under extreme acidic conditions. The rate constant for this process (5 × 10(-5) s(-1)) is pH independent and controlled by the cis-trans isomerization barrier. However, the interesting feature is the appearance of the colorless compound, 7,8-dihydro-6H-chromeno[3,2-d]xanthene, isolat…

Models MolecularXantheneMolecular StructureCyclohexanonesKineticsCyclohexanoneHydrogen-Ion ConcentrationPhotochemical ProcessesPhotochemistryChemical reactionAnthocyaninschemistry.chemical_compoundReaction rate constantchemistryBenzyl CompoundsProton NMRFlash photolysisPhysical and Theoretical Chemistryta116IsomerizationThe Journal of Physical Chemistry A
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CCDC 1558560: Experimental Crystal Structure Determination

2017

Related Article: Ildiko Buta, Liliana Cseh, Carmen Cretu, Diana Aparaschivei, Catalin Maxim, Peter Lönnecke, Evamarie Hey-Hawkins, Nicolae Stanica, Eva Ohler, Eva Rentschler, Marius Andruh, Otilia Costisor|2017|Inorg.Chim.Acta|475|133|doi:10.1016/j.ica.2017.10.024

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[bis(mu-22'-{piperazine-14-diylbis[(propane-31-diyl)azanylylidenemethylylidene]}diphenolato)-bis(mu-perchlorato)-nona-copper(ii) tetrakis(perchlorate) chloroform solvate]Cell ParametersExperimental 3D Coordinates
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CCDC 1558856: Experimental Crystal Structure Determination

2017

Related Article: Ildiko Buta, Liliana Cseh, Carmen Cretu, Diana Aparaschivei, Catalin Maxim, Peter Lönnecke, Evamarie Hey-Hawkins, Nicolae Stanica, Eva Ohler, Eva Rentschler, Marius Andruh, Otilia Costisor|2017|Inorg.Chim.Acta|475|133|doi:10.1016/j.ica.2017.10.024

Space GroupCrystallographyCrystal SystemCrystal Structurebis(acetato)-{mu-[2-{[(3-{4-[3-({[2-(hydroxy)phenyl]methylidene}amino)propyl]piperazin-1-yl}propyl)imino]methyl}phenolato]}-di-copper(ii)Cell ParametersExperimental 3D Coordinates
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CCDC 1006449: Experimental Crystal Structure Determination

2018

Related Article: Artur J. Moro, Ana-Maria Pana, Liliana Cseh, Otilia Costisor, Jorge Parola, L. Cunha-Silva, Rakesh Puttreddy, Kari Rissanen, and Fernando Pina|2014|J.Phys.Chem.A|118|6208|doi:10.1021/jp505533b

Space GroupCrystallography78-dihydro-6H-chromeno[32-d]xantheneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1558855: Experimental Crystal Structure Determination

2017

Related Article: Ildiko Buta, Liliana Cseh, Carmen Cretu, Diana Aparaschivei, Catalin Maxim, Peter Lönnecke, Evamarie Hey-Hawkins, Nicolae Stanica, Eva Ohler, Eva Rentschler, Marius Andruh, Otilia Costisor|2017|Inorg.Chim.Acta|475|133|doi:10.1016/j.ica.2017.10.024

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatestetrakis(mu-22'-{piperazine-14-diylbis[(propane-31-diyl)azanylylidenemethylylidene]}diphenolato)-bis(mu-azido)-hexa-copper(ii) bis(perchlorate)
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CCDC 1558561: Experimental Crystal Structure Determination

2017

Related Article: Ildiko Buta, Liliana Cseh, Carmen Cretu, Diana Aparaschivei, Catalin Maxim, Peter Lönnecke, Evamarie Hey-Hawkins, Nicolae Stanica, Eva Ohler, Eva Rentschler, Marius Andruh, Otilia Costisor|2017|Inorg.Chim.Acta|475|133|doi:10.1016/j.ica.2017.10.024

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu-22'-{piperazine-14-diylbis[(propane-31-diyl)azanylylidenemethylylidene]}diphenolato)-diaqua-tri-copper(ii) bis(perchlorate) trihydrateCell ParametersExperimental 3D Coordinates
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