0000000001311226
AUTHOR
Diana Aparaschivei
Polynuclear copper(II) complexes with hexadentate Schiff base directed by the counter ion. Syntheses, crystal structures and magnetic properties
Abstract Four new complexes, [Cu 9 L 6 ( µ 3 -ClO 4 ) 2 ](ClO 4 ) 4 ·4CHCl 3 1 , [Cu 3 L 2 (H 2 O) 2 ](ClO 4 ) 2 ·3H 2 O 2 , [Cu 6 L 4 (N 3 ) 2 ](ClO 4 ) 2 3 and [Cu 2 L(CH 3 COO) 2 ] 4 , where H 2 L stands for the Schiff base N , N ′-bis[(2-hydroxybenzilideneamino)-propyl]-piperazine, were obtained and structurally characterized. Compounds 1 , 2 and 3 contain the Cu 3 L 2 2+ entities in which L 2− acts in an unsymmetrical mode with N 3 O donor set wrapped around marginal copper(II) and with the remained NO sets bound to the central copper ion. The marginal copper(II) ions are in distorted square pyramidal environment, whereas that of the central one is square planar. In 1 , the peripheral …
CCDC 1558560: Experimental Crystal Structure Determination
Related Article: Ildiko Buta, Liliana Cseh, Carmen Cretu, Diana Aparaschivei, Catalin Maxim, Peter Lönnecke, Evamarie Hey-Hawkins, Nicolae Stanica, Eva Ohler, Eva Rentschler, Marius Andruh, Otilia Costisor|2017|Inorg.Chim.Acta|475|133|doi:10.1016/j.ica.2017.10.024
CCDC 1558856: Experimental Crystal Structure Determination
Related Article: Ildiko Buta, Liliana Cseh, Carmen Cretu, Diana Aparaschivei, Catalin Maxim, Peter Lönnecke, Evamarie Hey-Hawkins, Nicolae Stanica, Eva Ohler, Eva Rentschler, Marius Andruh, Otilia Costisor|2017|Inorg.Chim.Acta|475|133|doi:10.1016/j.ica.2017.10.024
CCDC 1558855: Experimental Crystal Structure Determination
Related Article: Ildiko Buta, Liliana Cseh, Carmen Cretu, Diana Aparaschivei, Catalin Maxim, Peter Lönnecke, Evamarie Hey-Hawkins, Nicolae Stanica, Eva Ohler, Eva Rentschler, Marius Andruh, Otilia Costisor|2017|Inorg.Chim.Acta|475|133|doi:10.1016/j.ica.2017.10.024
CCDC 1558561: Experimental Crystal Structure Determination
Related Article: Ildiko Buta, Liliana Cseh, Carmen Cretu, Diana Aparaschivei, Catalin Maxim, Peter Lönnecke, Evamarie Hey-Hawkins, Nicolae Stanica, Eva Ohler, Eva Rentschler, Marius Andruh, Otilia Costisor|2017|Inorg.Chim.Acta|475|133|doi:10.1016/j.ica.2017.10.024