0000000001311249
AUTHOR
Arup Mahata
Limiting nuclearity in formation of polynuclear metal complexes through [2 + 3] cycloaddition: synthesis and magnetic properties of tri- and pentanuclear metal complexes
A tridentate ligand p-chloro-2-{(2-(dimethylamino)ethylimino)methyl}phenol (HL) was used to generate an octahedral nickel complex [Ni(L)Cl(H2O)2] 1 which was further converted into a square-planar nickel complex [Ni(L)(N3)] 2. The [2 + 3] cycloaddition reaction between metal coordinated azide 2 and different organonitriles under microwave irradiation afforded tri- and pentanuclear nickel(II) complexes 4a-4c. Reaction with benzonitrile and 3-cyano pyridine furnished the trinuclear species [Ni3L2(5-phenyltetrazolato)4(DMF)2] 4a and [Ni3L2{5-(3-pyridyl)-tetrazolato}4(DMF)2]·2H2O 4b, respectively. The nickel centers were found to be linearly disposed to each other and the complex is formed by a…
CCDC 961048: Experimental Crystal Structure Determination
Related Article: Manideepa Saha, Rajendar Nasani, Mriganka Das, Arup Mahata, Biswarup Pathak, Shaikh M. Mobin, Luca M. Carrella, Eva Rentschler, Suman Mukhopadhyay|2014|Dalton Trans.|43|8083|doi:10.1039/C4DT00378K
CCDC 961049: Experimental Crystal Structure Determination
Related Article: Manideepa Saha, Rajendar Nasani, Mriganka Das, Arup Mahata, Biswarup Pathak, Shaikh M. Mobin, Luca M. Carrella, Eva Rentschler, Suman Mukhopadhyay|2014|Dalton Trans.|43|8083|doi:10.1039/C4DT00378K
CCDC 961050: Experimental Crystal Structure Determination
Related Article: Manideepa Saha, Rajendar Nasani, Mriganka Das, Arup Mahata, Biswarup Pathak, Shaikh M. Mobin, Luca M. Carrella, Eva Rentschler, Suman Mukhopadhyay|2014|Dalton Trans.|43|8083|doi:10.1039/C4DT00378K
CCDC 984713: Experimental Crystal Structure Determination
Related Article: Manideepa Saha, Rajendar Nasani, Mriganka Das, Arup Mahata, Biswarup Pathak, Shaikh M. Mobin, Luca M. Carrella, Eva Rentschler, Suman Mukhopadhyay|2014|Dalton Trans.|43|8083|doi:10.1039/C4DT00378K