0000000001311452

AUTHOR

Avishek Majumder

showing 8 related works from this author

Aromatic dicarboxylate incorporated new di- and tetranuclear cobalt(II) complexes: Synthetic and structural aspects, and evaluation of properties and…

2020

Abstract The synthetic and structural aspects as well as evaluation of magnetic properties and catalytic activity toward aerial oxidation of 3,5-di-tert-butylcatechol to 3,5-di-tert-butylbenzoquinone of three new, two di- and one tetranuclear cobalt(II) complexes, [Co2(cpdp)(Hphth)]∙5H2O (1), [Co2(cpdp)(Hisophth)] (2) and [Co4(cpdp)2(terephth)]∙4.5CH3OH·5.5H2O (3), based on a symmetrical multidentate ligand, N,N'-Bis[2-carboxybenzomethyl]-N,N'-Bis[2-pyridylmethyl]-1,3-diaminopropan-2-ol (H3cpdp) in combination with exogeneous aromatic dicarboxylic acids, such as phthalic acid (H2phth), isophthalic acid (H2isophth) and terephthalic acid (H2terephth) are reported. All three coordination compl…

Terephthalic acidDenticity010405 organic chemistryLigandchemistry.chemical_element010402 general chemistry01 natural sciencesSquare pyramidal molecular geometry0104 chemical sciencesInorganic ChemistryIsophthalic acidchemistry.chemical_compoundTrigonal bipyramidal molecular geometryCrystallographyPhthalic acidchemistryMaterials ChemistryPhysical and Theoretical ChemistryCobaltInorganica Chimica Acta
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Exploring new water soluble bridged dicopper(II) assemblies: Synthesis, structure, spectroscopic characterization, properties, and their interactions…

2021

Abstract Three new water soluble dimetallic copper(II) complexes, [Cu(H2O)5][Cu2(cpdp)(µ-O2As(CH3)2)]2Br2·13.83H2O·0.67CH3OH (1), [Cu2(Hcpdp)(µ-SO4)]·5H2O (2) and [Cu2(cpdp)(µ-pz)]·16H2O (3) (H3cpdp = N,N′-Bis[2-carboxybenzomethyl]-N,N′-Bis[2-pyridylmethyl]-1,3-diaminopropan-2-ol; (CH3)2AsO2− = cacodylate; SO42− = sulfate; pz− = pyrazolate) have been successfully synthesized and characterized for the investigation of coordination/binding aspects with biologically significant monosaccharide, d -glucosamine. Preparation of 1, 2 and 3 has been achieved by carrying out reaction of H3cpdp with stoichiometric quantities of CuCl2·2H2O/NaO2As(CH3)2·3H2O, CuSO4·5H2O and CuCl2·2H2O/1H-pyrazole, respe…

Aqueous solutionChemistrychemistry.chemical_elementCopperBinding constantMagnetic susceptibilityInorganic ChemistryMetalCrystallographyvisual_artMaterials Chemistryvisual_art.visual_art_mediumTitrationPhysical and Theoretical ChemistrySingle crystalStoichiometryPolyhedron
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Synthesis, structure and properties of a novel self-assembled tetranuclear copper(II) complex derived from carboxylate-based multidentate ligand

2020

Abstract A novel tetranuclear copper(II) complex, [Cu(H2O)5][Cu4(cpdp)2(adip)]ClBr∙2CH3OH·8H2O (1) of carboxylate-based symmetrical multidentate ligand, H3cpdp [H3cpdp = N,N'-Bis[2-carboxybenzomethyl]-N,N'-Bis[2-pyridylmethyl]-1,3-diaminopropan-2-ol; adip = adipate], has been synthesized and fully characterized. Complex 1 has been synthesized by carrying out reaction of ligand H3cpdp with stoichiometric amounts of CuCl2·2H2O/Na2(CH2CH2COO)2 in methanol-water in the presence of NaOH at room temperature. The solid state structure of 1 consists of a [Cu4(µ4-adip)] core unit which is held together by two multidentate bridging ligands, cpdp3−. In fact, complex 1 can be viewed as a “dimer-of-dime…

Thermogravimetric analysisDenticityLigandchemistry.chemical_element02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesCopperMagnetic susceptibility0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryAdipateMaterials ChemistryCarboxylatePhysical and Theoretical Chemistry0210 nano-technologyStoichiometryInorganic Chemistry Communications
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CCDC 2074991: Experimental Crystal Structure Determination

2021

Related Article: Avishek Majumder, Nityananda Dutta, Arpan Das, Luca Carrella, Manindranath Bera|2021|Polyhedron|208|115417|doi:10.1016/j.poly.2021.115417

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatespenta-aqua-copper(ii) dibromide bis(mu-dimethylarsinato)-(mu-22'-[(2-oxidopropane-13-diyl)bis({[(pyridin-2-yl)methyl]azanediyl}methylene)]dibenzoato)-di-copper(ii) methanol solvate hydrate
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CCDC 1984026: Experimental Crystal Structure Determination

2020

Related Article: Avishek Majumder, Nityananda Dutta, Shobhraj Haldar, Arpan Das, Luca Carrella, Manindranath Bera|2020|Inorg.Chim.Acta|510|119752|doi:10.1016/j.ica.2020.119752

(mu-hydrogen phthalato)-{mu-[2-({[3-({[2-carboxylatophenyl]methyl}[(pyridin-2-yl)methyl]amino)-2-oxypropyl][(pyridin-2-yl)methyl]amino}methyl)benzoato]}-di-cobalt pentahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2007743: Experimental Crystal Structure Determination

2021

Related Article: Nityananda Dutta, Shobhraj Haldar, Avishek Majumder, Gonela Vijaykumar, Luca Carrella, Manindranath Bera|2020|Inorg.Chem.Commun.|121|108208|doi:10.1016/j.inoche.2020.108208

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterspenta-aqua-copper(ii) bis(mu-22'-[(2-oxidopropane-13-diyl)bis({[(pyridin-2-yl)methyl]azanediyl}methylene)]dibenzoato)-(mu-hexanedioato)-tetra-copper(ii) bromide chloride methanol solvate octahydrateExperimental 3D Coordinates
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CCDC 2074992: Experimental Crystal Structure Determination

2021

Related Article: Avishek Majumder, Nityananda Dutta, Arpan Das, Luca Carrella, Manindranath Bera|2021|Polyhedron|208|115417|doi:10.1016/j.poly.2021.115417

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-22'-[(2-hydroxypropane-13-diyl)bis({[(pyridin-2-yl)methyl]azanediyl}methylene)]dibenzoato)-[mu-sulfato]-di-copper(ii) pentahydrateExperimental 3D Coordinates
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CCDC 1984027: Experimental Crystal Structure Determination

2020

Related Article: Avishek Majumder, Nityananda Dutta, Shobhraj Haldar, Arpan Das, Luca Carrella, Manindranath Bera|2020|Inorg.Chim.Acta|510|119752|doi:10.1016/j.ica.2020.119752

Space GroupCrystallographybis(mu-22'-[(2-oxypropane-13-diyl)bis({[(pyridin-2-yl)methyl]azanediyl}methylene)]dibenzoato)-(mu-terephthalato)-tetra-cobalt methanol solvate hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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