0000000001311603
AUTHOR
Beatriz Feringán
On the Structure and Chiral Aggregation of Liquid Crystalline Star‐Shaped Triazines H‐Bonded to Benzoic Acids
The ability of a star-shaped tris(triazolyl)triazine derivative to hierarchically build supramolecular chiral columnar organizations through the formation of H-bonded complexes with benzoic acids was studied from a theoretical and experimental point of view. The combined study has been done at three different levels including the study of the structure of the triazine core, the association with benzoic acids in stoichiometry 1:3, and the assembly of 1:3 complexes in helical aggregates. Although the star-shaped triazine core crystallizes in a non-C3 conformation, the C3 -symmetric conformation is theoretically predicted to be more stable and gives rise to a favorable C3 supramolecular 1:3 co…
CCDC 1986850: Experimental Crystal Structure Determination
Related Article: Beatriz Feringán, Jesús Cerdá, Beatriz Diosdado, Juan Aragó, Enrique Ortí, Raquel Giménez, Teresa Sierra|2020|Chem.-Eur.J.|26|15313|doi:10.1002/chem.202001271