0000000001311779

AUTHOR

Virginia Torres

showing 2 related works from this author

Heterometallic Titanium-Organic Frameworks as Dual Metal Catalysts for Synergistic Non-Buffered Hydrolysis of Nerve Agent Simulants

2020

Heterometallic metal-organic frameworks (MOFs) can offer important advantages over their homometallic counterparts to enable targeted modification of their adsorption, structural response, electronic structure, or chemical reactivity. However, controlling metal distribution in these solids still remains a challenge. The family of mesoporous titanium-organic frameworks, MUV-101(M), displays heterometallic TiM2 nodes assembled from direct reaction of Ti(IV) and M(II) salts. We use the degradation of nerve agent simulants to demonstrate that only TiFe2 nodes are capable of catalytic degradation in non-buffered conditions. By using an integrative experimental-computational approach, we rational…

General Chemical Engineeringchemistry.chemical_element02 engineering and technology010402 general chemistryHeterogeneous catalysis01 natural sciencesBiochemistryCatalysisMetalchemistry.chemical_compoundHydrolysisMaterials ChemistryEnvironmental ChemistrySynergistic catalysisLewis acids and basesBimetallic stripBiochemistry (medical)General ChemistryPurple acid phosphatases021001 nanoscience & nanotechnologyCombinatorial chemistry0104 chemical scienceschemistryvisual_artvisual_art.visual_art_mediumChemical stabilityTrimesic acid0210 nano-technologyBrønsted–Lowry acid–base theoryTitanium
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CCDC 1960226: Experimental Crystal Structure Determination

2020

Related Article: Javier Castells-Gil, Natalia M. Padial, Neyvis Almora-Barrios, Rodrigo Gil-San-Millán, María Romero-Ángel, Virginia Torres, Iván da Silva, Bruno C.J. Vieira, Joao C. Waerenborgh, Jaciek Jagiello, Jorge A.R. Navarro, Sergio Tatay, Carlos Martí-Gastaldo|2020|Cell Press: Chem|6|3118|doi:10.1016/j.chempr.2020.09.002

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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