Author: Jing Ma

0000000001311800

AUTHOR

Jing Ma

Breathing effect in a cobalt phosphonate upon dehydration/rehydration: a single-crystal-to-single-crystal study.

Two cobalt phosphonates, [Co2(2,2′-bpy)2(H2O)(pbtcH)] (1) and [Co2(H2O)(pbtcH)(phen)2] (2; pbtcH5=5-phosphonatophenyl-1,2,4-tricarboxylic acid, 2,2′-bpy=2,2′-bipyridine, phen=1,10-phenanthroline), with layer structures are reported. Compound 1 contains O-C-O and O-P-O bridged tetramers of Co4, which are further connected by pbtcH(4-) units to form a layer. In compound 2, the cobalt tetramers made up of water-bridged Co2 dimers and O-P-O linkages are connected into a layer by pbtcH(4-) units. Upon dehydration, compounds 1 and 2 experience single-crystal-to-single-crystal (SC-SC) structural transformations to form [Co2(2,2′-bpy)2(pbtcH)] (1 a) and [Co2(pbtcH)(phen)2] (2 a), respectively. The …

research product

CCDC 912971: Experimental Crystal Structure Determination

Related Article: Tao Zheng, Juan M. Clemente-Juan, Jing Ma, Lin Dong, Song-Song Bao, Jian Huang, Eugenio Coronado, Li-Min Zheng|2013|Chem.-Eur.J.|19|16394|doi:10.1002/chem.201302514

research product

CCDC 912969: Experimental Crystal Structure Determination

Related Article: Tao Zheng, Juan M. Clemente-Juan, Jing Ma, Lin Dong, Song-Song Bao, Jian Huang, Eugenio Coronado, Li-Min Zheng|2013|Chem.-Eur.J.|19|16394|doi:10.1002/chem.201302514

research product

CCDC 912972: Experimental Crystal Structure Determination

Related Article: Tao Zheng, Juan M. Clemente-Juan, Jing Ma, Lin Dong, Song-Song Bao, Jian Huang, Eugenio Coronado, Li-Min Zheng|2013|Chem.-Eur.J.|19|16394|doi:10.1002/chem.201302514

research product

CCDC 912970: Experimental Crystal Structure Determination

Related Article: Tao Zheng, Juan M. Clemente-Juan, Jing Ma, Lin Dong, Song-Song Bao, Jian Huang, Eugenio Coronado, Li-Min Zheng|2013|Chem.-Eur.J.|19|16394|doi:10.1002/chem.201302514

research product

CCDC 912973: Experimental Crystal Structure Determination

Related Article: Tao Zheng, Juan M. Clemente-Juan, Jing Ma, Lin Dong, Song-Song Bao, Jian Huang, Eugenio Coronado, Li-Min Zheng|2013|Chem.-Eur.J.|19|16394|doi:10.1002/chem.201302514

research product

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