0000000001312073

AUTHOR

Xiaojun Gu

showing 4 related works from this author

Influence of metal ions on the structures of Keggin polyoxometalate-based solids: Hydrothermal syntheses, crystal structures and magnetic properties

2006

Abstract Three new Keggin polyoxometalate (POM)-based compounds linked to 3d metal complexes have been synthesized under hydrothermal conditions: [Cu(phen)2]2{[Cu(phen)]2 [SiMo12O40(VO)2]} (1), {[Zn(phen)2]2[GeMo12O40(VO)2]}{[Zn(phen)2(H2O)]2 [GeMo12O40(VO)2]}·3H2O (2) and {[Co(phen)2]2[PMo12O40(VO)2]}{[Co(phen)2(OH)]2 [PMo12O40(VO)2]}·2.5H2O (3) (phen=1,10-phenanthroline). These three compounds present, as building blocks, the bicapped Keggin anions [XMo12O40(VO)2] (X=Si, Ge and P). Compound 1 consists of a bicapped Keggin anion [SiMo12O40(VO)2]2− linked to two [Cu(phen)]+ complexes with two [Cu(phen)2]+ countercations. Compound 2 contains two bicapped Keggin anions [GeMo12O40(VO)2]4−, one…

Bond valence methodPhenanthrolineMetal ions in aqueous solutionInorganic chemistryCrystal structureCondensed Matter PhysicsMagnetic susceptibilityElectronic Optical and Magnetic Materialslaw.inventionInorganic Chemistrychemistry.chemical_compoundCrystallographychemistrylawPolyoxometalateMaterials ChemistryCeramics and CompositesHydrothermal synthesisPhysical and Theoretical ChemistryElectron paramagnetic resonanceJournal of Solid State Chemistry
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CCDC 261263: Experimental Crystal Structure Determination

2006

Related Article: Zhenyu Shi, Jun Peng, C.J.Gomez-Garcia, S.Benmansour, Xiaojun Gu|2006|J.Solid State Chem.|179|253|doi:10.1016/j.jssc.2005.09.051

(mu~10~-Phosphato)-octakis(mu~3~-oxo)-octadecakis(mu~2~-oxo)-tetrakis(110-phenanthroline)-dodecaoxo-di-cobalt(ii)-tetra-molybdenum(v)-octa-molybdenum(vi)-di-vanadium(iv) (mu~10~-phosphato)-octakis(mu~3~-oxo)-octadecakis(mu~2~-oxo)-dihydroxy-tetrakis(110-phenanthroline)-dodecaoxo-di-cobalt(ii)-tetra-molybdenum(v)-octa-molybdenum(vi)-di-vanadium(iv) hydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 261262: Experimental Crystal Structure Determination

2006

Related Article: Zhenyu Shi, Jun Peng, C.J.Gomez-Garcia, S.Benmansour, Xiaojun Gu|2006|J.Solid State Chem.|179|253|doi:10.1016/j.jssc.2005.09.051

Space GroupCrystallographyCrystal System(mu~12~-Germanato)-octakis(mu~3~-oxo)-octadecakis(mu~2~-oxo)-tetrakis(110-phenanthroline)-dodecaoxo-tetra-molybdenum(v)-octa-molybdenum(vi)-di-vanadium(iv)-di-zinc(ii) (mu~12~-germanato)-octakis(mu~3~-oxo)-octadecakis(mu~2~-oxo)-diaqua-tetrakis(110-phenanthroline)-dodecaoxo-tetra-molybdenum(v)-octa-molybdenum(vi)-di-vanadium(iv)-di-zinc(ii) trihydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 265898: Experimental Crystal Structure Determination

2006

Related Article: Zhenyu Shi, Jun Peng, C.J.Gomez-Garcia, S.Benmansour, Xiaojun Gu|2006|J.Solid State Chem.|179|253|doi:10.1016/j.jssc.2005.09.051

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu~10~-Silicato)-octakis(mu~3~-oxo)-octadecakis(mu~2~-oxo)-bis(110-phenanthroline)-dodecaoxo-di-copper(i)-tetra-molybdenum(v)-octa-molybdenum(vi)-di-vanadium(iv) bis(bis(110-phenanthroline)-copper(i))Experimental 3D Coordinates
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