0000000001312073
AUTHOR
Xiaojun Gu
Influence of metal ions on the structures of Keggin polyoxometalate-based solids: Hydrothermal syntheses, crystal structures and magnetic properties
Abstract Three new Keggin polyoxometalate (POM)-based compounds linked to 3d metal complexes have been synthesized under hydrothermal conditions: [Cu(phen)2]2{[Cu(phen)]2 [SiMo12O40(VO)2]} (1), {[Zn(phen)2]2[GeMo12O40(VO)2]}{[Zn(phen)2(H2O)]2 [GeMo12O40(VO)2]}·3H2O (2) and {[Co(phen)2]2[PMo12O40(VO)2]}{[Co(phen)2(OH)]2 [PMo12O40(VO)2]}·2.5H2O (3) (phen=1,10-phenanthroline). These three compounds present, as building blocks, the bicapped Keggin anions [XMo12O40(VO)2] (X=Si, Ge and P). Compound 1 consists of a bicapped Keggin anion [SiMo12O40(VO)2]2− linked to two [Cu(phen)]+ complexes with two [Cu(phen)2]+ countercations. Compound 2 contains two bicapped Keggin anions [GeMo12O40(VO)2]4−, one…
CCDC 261263: Experimental Crystal Structure Determination
Related Article: Zhenyu Shi, Jun Peng, C.J.Gomez-Garcia, S.Benmansour, Xiaojun Gu|2006|J.Solid State Chem.|179|253|doi:10.1016/j.jssc.2005.09.051
CCDC 261262: Experimental Crystal Structure Determination
Related Article: Zhenyu Shi, Jun Peng, C.J.Gomez-Garcia, S.Benmansour, Xiaojun Gu|2006|J.Solid State Chem.|179|253|doi:10.1016/j.jssc.2005.09.051
CCDC 265898: Experimental Crystal Structure Determination
Related Article: Zhenyu Shi, Jun Peng, C.J.Gomez-Garcia, S.Benmansour, Xiaojun Gu|2006|J.Solid State Chem.|179|253|doi:10.1016/j.jssc.2005.09.051