Author: F.w. Patureau

0000000001312331

AUTHOR

F.w. Patureau

showing 3 related works from this author

Supramolecular hydrogen-bonding tautomeric sulfonamido-phosphinamides: a perfect P-chirogenic memory

2011

P-chirogenic, supramolecular hydrogen-bonding C1-symmetrical sulfonamido–phosphinamides (METAMORPhos) have been successfully prepared. They were all found to possess a characteristic prototropic equilibrium between the PIII and the PV tautomers that is slow on the NMR spectroscopic timescale. Despite the dynamic and reversible protonation of the P centre, the P-chirogenic information was found to be retained in the tautomerization process, even in a protic solvent environment. Several strategies to access the corresponding enantiopure compounds were investigated, such as diastereoselective crystallization, or enantioselective synthesis. It was possible to resolve such a class of chiral liga…

Inorganic Chemistrychemistry.chemical_compoundEnantiopure drugchemistryStereochemistryLigandAsymmetric hydrogenationSupramolecular chemistryEnantioselective synthesisProtonationCombinatorial chemistryTautomerProtic solventEuropean Journal of Inorganic Chemistry

researchProduct

CCDC 836863: Experimental Crystal Structure Determination

2012

Related Article: F.W.Patureau, M.A.Siegler, A.L.Spek, A.J.Sandee, S.Juge, S.Aziz, A.Berkessel, J.N.H.Reek|2012|Eur.J.Inorg.Chem.||496|doi:10.1002/ejic.201100811

Space GroupCrystallographyCrystal System4-Butyl-N-((22'-dimethoxy-11'-binaphthalen-3-yl)(phenyl)phosphino)benzenesulfonamideCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 836862: Experimental Crystal Structure Determination

2012

Related Article: F.W.Patureau, M.A.Siegler, A.L.Spek, A.J.Sandee, S.Juge, S.Aziz, A.Berkessel, J.N.H.Reek|2012|Eur.J.Inorg.Chem.||496|doi:10.1002/ejic.201100811

Space GroupCrystallographyCrystal System4-Butyl-N-((2-methoxyphenyl)(phenyl)phosphino)benzenesulfonamideCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

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