0000000001312461

AUTHOR

Johnny Hu

showing 2 related works from this author

A Bis‐Acridinium Macrocycle as Multi‐Responsive Receptor and Selective Phase‐Transfer Agent of Perylene

2020

A bis‐acridinium cyclophane incorporating switchable acridinium moieties linked by a 3,5‐dipyridylanisole spacer was studied as a multi‐responsive host for polycyclic aromatic hydrocarbon guests. Complexation of perylene was proven to be the most effective and was characterized in particular by a charge transfer band as signal output. Effective catch and release of the guest was triggered by both chemical (proton/hydroxide) and redox stimuli. Moreover, the dicationic host was also easily switched between organic and perfluorocarbon phases for application related to the enrichment of perylene from a mixture of polycyclic aromatic hydrocarbons. peerReviewed

Polycyclic aromatic hydrocarbon010402 general chemistryRedox01 natural sciencesCatalysischemistry.chemical_compoundTransfer agentPhase (matter)PFC-yhdisteetsupramolekulaarinen kemia[CHIM]Chemical Scienceshost-guest chemistryHost–guest chemistryComputingMilieux_MISCELLANEOUSmulti-responsive receptorchemistry.chemical_classificationacridinium[CHIM.ORGA]Chemical Sciences/Organic chemistry010405 organic chemistryGeneral ChemistryGeneral MedicineperfluorocarbonsCombinatorial chemistry0104 chemical sciencesisäntä-vieras kemiachemistryHydroxidephase transferPeryleneCyclophane
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CCDC 2003776: Experimental Crystal Structure Determination

2020

Related Article: Johnny Hu, Jas S. Ward, Alain Chaumont, Kari Rissanen, Jean-Marc Vincent, Valérie Heitz, Henri-Pierre Jacquot de Rouville|2020|Angew.Chem.,Int.Ed.|59|23206|doi:10.1002/anie.202009212

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters9-methoxy-24436264-tetraazadecacyclo[41.6.6.61724.126.1711.11216.01823.04449.05055.05661]tetrahexaconta-1(49)2(64)357(63)81012(62)13151719212333434547505254565860-tetracosaene-2443-diium bis(hexafluoridophosphate) benzene solvateExperimental 3D Coordinates
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