0000000001312488
AUTHOR
Shizhen Du
showing 10 related works from this author
Constrained formation of 2-(1-(arylimino)ethyl)-7-arylimino-6,6-dimethylcyclopentapyridines and their cobalt(ii) chloride complexes: synthesis, chara…
2015
A series of 2-(1-(arylimino)ethyl)-7-arylimino-6,6-dimethylcyclopentapyridine derivatives (L1-L5) was synthesized, and individually reacted with cobalt(II) chloride to form the corresponding cobalt chloride complexes (C1-C4). These compounds were characterized, and the single crystal X-ray diffraction for two representative cobalt complexes was carried out. The molecular structures indicate that 2,7-bis(arylimino)cyclopentapyridines act as tridentate ligands; however, one of the Co-N coordinative bonds is weak due to the spatial separation of nitrogen atoms. Upon activation with either MAO or MMAO, all cobalt complexes exhibit catalytic activities toward ethylene. Polymerization takes place…
Ethylene polymerization by the thermally unique 1-[2-(bis(4-fluoro phenyl)methyl)-4,6- dimethylphenylimino]-2-aryliminoacenaphthylnickel precursors
2015
A series of 1-[2-(bis(4-fluorophenyl)methyl)-4,6-dimethylphenylimino]-2-aryliminoacenaphthylene derivatives together with the corresponding nickel bromide complexes was synthesized and characterized. Representative complexes C2 and C5 were characterized by the single-crystal X-ray diffraction, revealing a distorted tetrahedral geometry. Upon activation with either methylaluminoxane (MAO) or ethylaluminum sesquichloride (EASC), all nickel complexes exhibited high activities towards ethylene polymerization, producing polyethylene with a relatively low degree of branching and narrow polydispersity. Complex C1 maintained good activity at elevated reaction temperatures, which indicates significa…
Propyl substituted 4-arylimino-1,2,3-trihydroacridylnickel complexes: Their synthesis, characterization and catalytic behavior toward ethylene
2015
Propyl substituted 4-arylimino-1,2,3-trihydroacridylnickel dihalide complexes were designed and prepared by metal-induced template reaction with NiCl2 center dot 6H(2)O or (DME)NiBr2. They were characterized by infrared spectroscopy and elemental analysis. Single crystal X-ray crystallography of representative complex Ni3 revealed a distorted trigonal bipyramidal geometry around nickel. The catalytic activities of the title nickel complexes were negatively affected by propyl substituent on their backbone when comparing with the results by unsubstituted ones. With the activation of diethylaluminium chloride, all nickel complexes exhibited moderate activity (up to 5.10 x 10(5) g mol(-1)(Ni) h…
A practical ethylene polymerization for vinyl-polyethylenes: synthesis, characterization and catalytic behavior of α,α’-bisimino-2,3:5,6- bis(pentame…
2016
A series of α,α′-bis(arylimino)-2,3:5,6-bis(pentamethylene)pyridyliron chlorides was synthesized in a one-pot reaction and characterized by FT-IR and elemental analysis as well as X-ray crystallography for one representative iron complex, where the Fe center adopts a distorted square pyramidal geometry with three coordinating nitrogen and two chlorine atoms. The iron precatalysts, upon treatment with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO), exhibit high activities in the range of 107 g of PE per mol of Fe per h toward ethylene polymerization, yielding highly linear and, more importantly, vinyl-polyethylenes. The correlation between the structural features of iron…
CCDC 1476785: Experimental Crystal Structure Determination
2016
Related Article: Shizhen Du, Xinxin Wang, Wenjuan Zhang, Zygmunt Flisak, Yang Sun, Wen-Hua Sun|2016|Polym.Chem.|7|4188|doi:10.1039/C6PY00745G
CCDC 1042277: Experimental Crystal Structure Determination
2015
Related Article: Shizhen Du, Qifeng Xing, Zygmunt Flisak, Erlin Yue, Yang Sun, Wen-Hua Sun|2015|Dalton Trans.|44|12282|doi:10.1039/C5DT00052A
CCDC 1054235: Experimental Crystal Structure Determination
2015
Related Article: Junjun Ba, Shizhen Du, Erlin Yue, Xinquan Hu, Zygmunt Flisak, Wen-Hua Sun|2015|RSC Advances|5|32720|doi:10.1039/C5RA04722F
CCDC 1043484: Experimental Crystal Structure Determination
2015
Related Article: Shengdong Wang, Wenjuan Zhang, Shizhen Du, Sin Asuha, Zygmunt Flisak, Wen-Hua Sun|2015|J.Organomet.Chem.|798|408|doi:10.1016/j.jorganchem.2015.05.001
CCDC 1042276: Experimental Crystal Structure Determination
2015
Related Article: Shizhen Du, Qifeng Xing, Zygmunt Flisak, Erlin Yue, Yang Sun, Wen-Hua Sun|2015|Dalton Trans.|44|12282|doi:10.1039/C5DT00052A
CCDC 1054234: Experimental Crystal Structure Determination
2015
Related Article: Junjun Ba, Shizhen Du, Erlin Yue, Xinquan Hu, Zygmunt Flisak, Wen-Hua Sun|2015|RSC Advances|5|32720|doi:10.1039/C5RA04722F