0000000001312690
AUTHOR
Eric Milin
showing 8 related works from this author
Hepta- and tetra-nuclear copper(II) clusters self-assembled by cyano- and azacyano-carbanions
2015
International audience; Two polynuclear copper(II) complexes with hydroxido-bridging ligands and polycyanide units, [Cu{Cu(tn)}6(μ2-OH)2(μ3-OH)4Cl2](tcm)4Cl2·2H2O (1) and [{Cu(bpy)}4(OH)4(dca)2](dca)2·bpy·2H2O (2) (tn = NH2(CH2)3NH2; tcm− = [C(CN)3]−, bpy = 2,2′-bipyridyl, dca− = [N(CN)2]−) have been prepared by one-pot reactions. The structure of 1 consists of a centrosymmetric heptanuclear ion [Cu{Cu(tn)}6(μ2-OH)2(μ3-OH)4Cl2]6+. The tcm− and the halide anions which appear as counter-ions in the formula unit, play an important role in the stabilization of the complex since the hydrogen bonding between nitrogen atoms of the tcm− anion and halide anions, and hydrogen atoms of the terminal wa…
Spin Crossover Iron(II) Coordination Polymer Chains: Syntheses, Structures, and Magnetic Characterizations of [Fe(aqin) 2 (μ 2 -M(CN) 4 )] (M = Ni(II…
2014
International audience; New Fe(II) coordination polymeric neutral chains of formula [Fe(aqin)2(μ2-M(CN)4)] (M = NiII (1) and PtII (2)) (aqin = Quinolin-8-amine) have been synthesized and characterized by infrared spectroscopy, X-ray diffraction, and magnetic measurements. The crystal structure determinations of 1–2 reveal in both cases a one-dimensional structure in which the planar [M(CN)4]2– (M = NiII (1) and PtII (2)) anion acts as a μ2-bridging ligand, and the two aqin molecules as chelating coligands. Examination of the intermolecular contacts in the two compounds reveals that the main contacts are ascribed to hydrogen bonding interactions involving the amine groups of the aqin chelati…
Front Cover: Magnetic Bistability in Macrocycle‐Based Fe II Spin‐Crossover Complexes: Counter Ion and Solvent Effects (Eur. J. Inorg. Chem. 34/2016)
2016
CCDC 931126: Experimental Crystal Structure Determination
2014
Related Article: Fatima Setifi, Eric Milin, Catherine Charles, Franck Thétiot, Smail Triki, and Carlos J. Gómez-García|2014|Inorg.Chem.|53|97|doi:10.1021/ic401721x
CCDC 1060081: Experimental Crystal Structure Determination
2015
Related Article: Smail Triki, Eric Milin, Carlos J. Gómez-García, Samia Benmansour, Mathieu Marchivie|2015|Polyhedron|98|18|doi:10.1016/j.poly.2015.05.037
CCDC 938438: Experimental Crystal Structure Determination
2014
Related Article: Fatima Setifi, Eric Milin, Catherine Charles, Franck Thétiot, Smail Triki, and Carlos J. Gómez-García|2014|Inorg.Chem.|53|97|doi:10.1021/ic401721x
CCDC 924208: Experimental Crystal Structure Determination
2014
Related Article: Fatima Setifi, Eric Milin, Catherine Charles, Franck Thétiot, Smail Triki, and Carlos J. Gómez-García|2014|Inorg.Chem.|53|97|doi:10.1021/ic401721x
CCDC 924207: Experimental Crystal Structure Determination
2014
Related Article: Fatima Setifi, Eric Milin, Catherine Charles, Franck Thétiot, Smail Triki, and Carlos J. Gómez-García|2014|Inorg.Chem.|53|97|doi:10.1021/ic401721x