0000000001312907

AUTHOR

De-en Jiang

showing 2 related works from this author

Gold Nanowired: A Linear (Au25)n Polymer from Au25 Molecular Clusters

2014

Au25(SR)18 has provided fundamental insights into the properties of clusters protected by monolayers of thiolated ligands (SR). Because of its ultrasmall core, 1 nm, Au25(SR)18 displays molecular behavior. We prepared a Au25 cluster capped by n-butanethiolates (SBu), obtained its structure by single-crystal X-ray crystallography, and studied its properties both experimentally and theoretically. Whereas in solution Au25(SBu)18(0) is a paramagnetic molecule, in the crystal it becomes a linear polymer of Au25 clusters connected via single Au-Au bonds and stabilized by proper orientation of clusters and interdigitation of ligands. At low temperature, [Au25(SBu)18(0)]n has a nonmagnetic ground s…

Materials sciencepolymerNanowireGeneral Physics and Astronomy02 engineering and technology010402 general chemistry01 natural sciencesparamagnetismCrystalParamagnetismAu25MonolayerCluster (physics)MoleculeGeneral Materials Scienceta116X-ray crystallographychemistry.chemical_classificationGeneral EngineeringPolymer021001 nanoscience & nanotechnology0104 chemical sciences3. Good healthCrystallographychemistryantiferromagnetic couplingX-ray crystallography0210 nano-technologygold nanoclusters
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CCDC 998586: Experimental Crystal Structure Determination

2014

Related Article: Marco De Nardi, Sabrina Antonello, De-en Jiang, Fangfang Pan, Kari Rissanen, Marco Ruzzi, Alfonso Venzo, Alfonso Zoleo, Flavio Maran|2014|ACS Nano|8|8505|doi:10.1021/nn5031143

catena-[hexatriacontakis(mu2-Butane-1-thiolato)-pentaconta-gold]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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