Author: Ruixuan Qin

0000000001313133

AUTHOR

Ruixuan Qin

showing 2 related works from this author

Surface Coordination of Multiple Ligands Endows N‐Heterocyclic Carbene‐Stabilized Gold Nanoclusters with High Robustness and Surface Reactivity

2020

Deciphering the molecular pictures of the multi-component and non-periodic organic-inorganic interlayer is a grand technical challenge. Here we show that the atomic arrangement of hybrid surface ligands on metal nanoparticles can be precisely quantified through comprehensive characterization of a novel gold cluster, Au 44 ( i Pr 2 -bimy) 9 (PA) 6 Br 8 , which features three types of ligands, namely, carbene (1,3-diisopropylbenzimidazolin-2-ylidene, i Pr 2 -bimy), alkynyl (phenylacetylide, PA), and halide (Br), respectively. The delicately balanced stereochemical effects and bonding capabilities of the three ligands give rise to peculiar geometrical and electronic structures. Remarkably, des…

Nanostructurecarbene ligandsHalidereaktiivisuus010402 general chemistry01 natural sciencesCatalysisCatalysisNanoclustersklusteritchemistry.chemical_compoundnanorakenteetnanostructuresCluster (physics)Gold clustercatalysis010405 organic chemistryChemistryGeneral MedicineGeneral Chemistry0104 chemical sciencesCrystallographykatalyysiYield (chemistry)rajapinnat (pinnat)cluster compoundssurface reactivitiesnanohiukkasetCarbeneAngewandte Chemie International Edition

researchProduct

CCDC 1998895: Experimental Crystal Structure Determination

2020

Related Article: Hui Shen, Zhen Xu, Maryam Sabooni Asre Hazer, Qingyuan Wu, Jiang Peng, Ruixuan Qin, Sam Malola, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2020|Angew.Chem.,Int.Ed.|60|3752|doi:10.1002/anie.202013718

hexakis(mu2-eta2-2-(phenyl)ethynyl)-nonakis(13-bis(propan-2-yl)-23-dihydro-1H-benzimidazol-2-ylidene)-octabromo-tetratetraconta-goldSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
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LSLife Sciences
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SHSocial Sciences and Humanities
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