0000000001313224

AUTHOR

Enrique García‐españa

showing 4 related works from this author

Characterization of a Ferryl Flip in Electronically Tuned Nonheme Complexes. Consequences in Hydrogen Atom Transfer Reactivity

2022

Two oxoiron(IV) isomers (R2a and R2b) of general formula [FeIV(O)(RPyNMe3)(CH3CN)]2+ are obtained by reaction of their iron(II) precursor with NBu4IO4. The two isomers differ in the position of the oxo ligand, cis and trans to the pyridine donor. The mechanism of isomerization between R2a and R2b has been determined by kinetic and computational analyses uncovering an unprecedented path for interconversion of geometrical oxoiron(IV) isomers. The activity of the two oxoiron(IV) isomers in hydrogen atom transfer (HAT) reactions shows that R2a reacts one order of magnitude faster than R2b, which is explained by a repulsive noncovalent interaction between the ligand and the substrate in R2b. Int…

General ChemistryGeneral MedicineCatalysisÀtomsReaccions químiquesAngewandte Chemie
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CCDC 1814350: Experimental Crystal Structure Determination

2018

Related Article: Raminder S. Mulla, Marikka S. Beecroft, Robert Pal, Juan A. Aguilar, Javier Pitarch‐Jarque, Enrique García‐España, Elena Lurie‐Luke, Gary J. Sharples, J. A. Gareth Williams|2018|Chem.-Eur.J.|24|7137|doi:10.1002/chem.201800026

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters22'-(ethane-12-diylbis((2-((carboxymethyl)amino)-2-oxoethyl)azaniumyl))diacetateExperimental 3D Coordinates
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CCDC 1814351: Experimental Crystal Structure Determination

2018

Related Article: Raminder S. Mulla, Marikka S. Beecroft, Robert Pal, Juan A. Aguilar, Javier Pitarch‐Jarque, Enrique García‐España, Elena Lurie‐Luke, Gary J. Sharples, J. A. Gareth Williams|2018|Chem.-Eur.J.|24|7137|doi:10.1002/chem.201800026

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(sodium) (58-bis(carboxylatomethyl)-310-dioxo-25811-tetraaza-dodecane-112-dicarboxylato)-aqua-magnesium(ii) nitrate heptahydrateExperimental 3D Coordinates
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CCDC 1814349: Experimental Crystal Structure Determination

2018

Related Article: Raminder S. Mulla, Marikka S. Beecroft, Robert Pal, Juan A. Aguilar, Javier Pitarch‐Jarque, Enrique García‐España, Elena Lurie‐Luke, Gary J. Sharples, J. A. Gareth Williams|2018|Chem.-Eur.J.|24|7137|doi:10.1002/chem.201800026

di-t-butyl 22'-(ethane-12-diylbis(benzylimino))diacetateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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