0000000001313429

AUTHOR

Antonin Leblanc

showing 2 related works from this author

A robust viologen and Mn-based porous coordination polymer with two types of Lewis acid sites providing high affinity for H 2 O, CO 2 and NH 3

2017

A novel porous coordination polymer [Mn(pc3)(H2O)2]·xH2O (3 < x < 4) is synthesized in water at pH = 7 using the anionic viologen-carboxylate ligand 4,4′-bipyridinium,1,1′-bis-(2,4-dicarboxyphenyl) (pc32−). Dehydration of the material results in the formation of open pores containing two types of accessible Lewis acid sites: exposed Mn2+ cations and N+ atoms of viologen units. Due to this property the PCP shows high affinity and capacity in the adsorption of H2O, CO2 and NH3. Despite the presence of strong adsorption sites this material is stable in liquid water and in gaseous NH3.

010405 organic chemistryLiquid waterCoordination polymerLigandInorganic chemistryViologen010402 general chemistrymedicine.disease01 natural sciences0104 chemical sciencesInorganic Chemistry[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistrychemistry.chemical_compoundAdsorptionchemistrymedicine[CHIM]Chemical SciencesLewis acids and basesDehydrationPorosityComputingMilieux_MISCELLANEOUSmedicine.drug
researchProduct

CCDC 1571877: Experimental Crystal Structure Determination

2018

Related Article: Antonin Leblanc, Nicolas Mercier, Magali Allain, Marie-Claire Dul, Guy Weber, Nicolas Geoffroy, Jean-Pierre Bellat, Igor Bezverkhyy|2017|Dalton Trans.|46|15666|doi:10.1039/C7DT03541A

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-((mu-55'-((44'-bipyridin-1-ium)-11'-diyl)bis(benzene-13-dicarboxylato))-diaqua-manganese(ii) trihydrate)Cell ParametersExperimental 3D Coordinates
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