Author: Christian Bissinger

0000000001313804

AUTHOR

Christian Bissinger

showing 3 related works from this author

Boosting Vis/NIR Charge-Transfer Absorptions of Iron(II) Complexes by N-Alkylation and N-Deprotonation in the Ligand Backbone.

2017

Reversing the 3MLCT / 3MC excited state order in iron(II) complexes is a challenging objective, yet would finally result in longsought luminescent transition metal complexes with an earthabundant central ion. One approach to achieve this goal is based on low-energy charge transfer absorptions in combination with a strong ligand field. Coordinating electron rich and electron poor tridentate oligopyridine ligands with large bite angles at iron(II) enables both low-energy MLCT absorption bands around 590 nm and a strong ligand field. Variations of the electron rich ligand by introducing longer alkyl substituents destabilizes the iron(II) complex towards ligand substitution reactions while hard…

chemistry.chemical_classificationLigand field theory010405 organic chemistryChemistryLigandBand gapOrganic ChemistryGeneral Chemistry010402 general chemistryPhotochemistry01 natural sciencesCatalysis0104 chemical sciencesDeprotonationTransition metalExcited stateDensity functional theoryAlkylChemistry (Weinheim an der Bergstrasse, Germany)

researchProduct

CCDC 1526745: Experimental Crystal Structure Determination

2017

Related Article: Andreas K. C. Mengel, Christian Bissinger, Matthias Dorn, Oliver Back, Christoph Förster, Katja Heinze|2017|Chem.-Eur.J.|23|7920|doi:10.1002/chem.201700959

bis(NN'-dihexyl-NN'-bis(pyridin-2-yl)pyridine-26-diamine)-iron bis(hexafluorophosphate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1526744: Experimental Crystal Structure Determination

2017

Related Article: Andreas K. C. Mengel, Christian Bissinger, Matthias Dorn, Oliver Back, Christoph Förster, Katja Heinze|2017|Chem.-Eur.J.|23|7920|doi:10.1002/chem.201700959

Space GroupCrystallography(NN'-bis(pyridin-2-yl)pyridine-26-diamine)-(pyridine-26-diylbis(pyridin-2-ylmethanone))-iron bis(hexafluorophosphate) hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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