0000000001313845
AUTHOR
Kristina Hanauer
Redox‐Controlled Stabilization of an Open‐Shell Intermediate in a Bioinspired Enzyme Model
Solution Conformation and Self‐Assembly of Ferrocenyl(thio)ureas
Conformations and (dis)assembly processes of ureas and thioureas are of fundamental importance in supramolecular chemistry, anion binding, or crystal engineering, both in solution and in the solid state. For sensing and switching processes a redox-active unit, such as the ferrocene/ferrocenium couple, is especially suitable. Here, self-assembly processes of redox-active ferrocenyl(thio)ureas FcNHC(X)NHR [X = O, R = Fc (1), Ph (2), 1-naphthyl (3), Me (4), Et (5); X = S, R = Fc (6), 1-anthracenyl (7)] through hydrogen bonds – both in the solid state and in THF and CH2Cl2 solution – are reported. Special emphasis is placed on the impact of nonclassical intramolecular NH···Fe hydrogen bonds in …
Front Cover: Redox‐Controlled Stabilization of an Open‐Shell Intermediate in a Bioinspired Enzyme Model (Eur. J. Inorg. Chem. 31/2018)
CCDC 1494856: Experimental Crystal Structure Determination
Related Article: Kristina Hanauer, Minh Thu Pham, Christoph Förster, Katja Heinze|2017|Eur.J.Inorg.Chem.||433|doi:10.1002/ejic.201600918
CCDC 1494853: Experimental Crystal Structure Determination
Related Article: Kristina Hanauer, Minh Thu Pham, Christoph Förster, Katja Heinze|2017|Eur.J.Inorg.Chem.||433|doi:10.1002/ejic.201600918
CCDC 1494855: Experimental Crystal Structure Determination
Related Article: Kristina Hanauer, Minh Thu Pham, Christoph Förster, Katja Heinze|2017|Eur.J.Inorg.Chem.||433|doi:10.1002/ejic.201600918
CCDC 1494851: Experimental Crystal Structure Determination
Related Article: Kristina Hanauer, Minh Thu Pham, Christoph Förster, Katja Heinze|2017|Eur.J.Inorg.Chem.||433|doi:10.1002/ejic.201600918
CCDC 1538078: Experimental Crystal Structure Determination
Related Article: Kristina Hanauer, Christoph Förster, and Katja Heinze|2018|Eur.J.Inorg.Chem.||3537|doi:10.1002/ejic.201800570
CCDC 1494858: Experimental Crystal Structure Determination
Related Article: Kristina Hanauer, Minh Thu Pham, Christoph Förster, Katja Heinze|2017|Eur.J.Inorg.Chem.||433|doi:10.1002/ejic.201600918
CCDC 1494852: Experimental Crystal Structure Determination
Related Article: Kristina Hanauer, Minh Thu Pham, Christoph Förster, Katja Heinze|2017|Eur.J.Inorg.Chem.||433|doi:10.1002/ejic.201600918
CCDC 1494857: Experimental Crystal Structure Determination
Related Article: Kristina Hanauer, Minh Thu Pham, Christoph Förster, Katja Heinze|2017|Eur.J.Inorg.Chem.||433|doi:10.1002/ejic.201600918
CCDC 1494854: Experimental Crystal Structure Determination
Related Article: Kristina Hanauer, Minh Thu Pham, Christoph Förster, Katja Heinze|2017|Eur.J.Inorg.Chem.||433|doi:10.1002/ejic.201600918
CCDC 1538079: Experimental Crystal Structure Determination
Related Article: Kristina Hanauer, Christoph Förster, and Katja Heinze|2018|Eur.J.Inorg.Chem.||3537|doi:10.1002/ejic.201800570