Author: S. Libri

0000000001313852

AUTHOR

S. Libri

Coordination Polymer Flexibility Leads to Polymorphism and Enables a Crystalline Solid-Vapour Reaction: A Multi-technique Mechanistic Study.

Despite an absence of conventional porosity, the 1D coordination polymer [Ag4 (O2 C(CF2 )2 CF3 )4 (TMP)3 ] (1; TMP=tetramethylpyrazine) can absorb small alcohols from the vapour phase, which insert into AgO bonds to yield coordination polymers [Ag4 (O2 C(CF2 )2 CF3 )4 (TMP)3 (ROH)2 ] (1-ROH; R=Me, Et, iPr). The reactions are reversible single-crystal-to-single-crystal transformations. Vapour-solid equilibria have been examined by gas-phase IR spectroscopy (K=5.68(9)×10(-5) (MeOH), 9.5(3)×10(-6) (EtOH), 6.14(5)×10(-5) (iPrOH) at 295 K, 1 bar). Thermal analyses (TGA, DSC) have enabled quantitative comparison of two-step reactions 1-ROH→1→2, in which 2 is the 2D coordination polymer [Ag4 (O2 C…

research product

CCDC 886502: Experimental Crystal Structure Determination

Related Article: G.M.Espallargas, A.Recuenco, F.M.Romero, L.Brammer, S.Libri|2012|CrystEngComm|14|6381|doi:10.1039/c2ce26131f

research product

CCDC 886501: Experimental Crystal Structure Determination

Related Article: G.M.Espallargas, A.Recuenco, F.M.Romero, L.Brammer, S.Libri|2012|CrystEngComm|14|6381|doi:10.1039/c2ce26131f

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PEPhysical Sciences and Engineering
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