0000000001313852

AUTHOR

S. Libri

showing 3 related works from this author

Coordination Polymer Flexibility Leads to Polymorphism and Enables a Crystalline Solid-Vapour Reaction: A Multi-technique Mechanistic Study.

2015

Despite an absence of conventional porosity, the 1D coordination polymer [Ag4 (O2 C(CF2 )2 CF3 )4 (TMP)3 ] (1; TMP=tetramethylpyrazine) can absorb small alcohols from the vapour phase, which insert into AgO bonds to yield coordination polymers [Ag4 (O2 C(CF2 )2 CF3 )4 (TMP)3 (ROH)2 ] (1-ROH; R=Me, Et, iPr). The reactions are reversible single-crystal-to-single-crystal transformations. Vapour-solid equilibria have been examined by gas-phase IR spectroscopy (K=5.68(9)×10(-5) (MeOH), 9.5(3)×10(-6) (EtOH), 6.14(5)×10(-5) (iPrOH) at 295 K, 1 bar). Thermal analyses (TGA, DSC) have enabled quantitative comparison of two-step reactions 1-ROH→1→2, in which 2 is the 2D coordination polymer [Ag4 (O2 C…

researchProduct

CCDC 886502: Experimental Crystal Structure Determination

2013

Related Article: G.M.Espallargas, A.Recuenco, F.M.Romero, L.Brammer, S.Libri|2012|CrystEngComm|14|6381|doi:10.1039/c2ce26131f

Space GroupCrystallographyCrystal System4455-Tetramethyl-2-phenyl-45-dihydro-1H-3lambda^5^-imidazole-13-diol 22'33'55'66'-octafluoro-44'-diiodobiphenylCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 886501: Experimental Crystal Structure Determination

2013

Related Article: G.M.Espallargas, A.Recuenco, F.M.Romero, L.Brammer, S.Libri|2012|CrystEngComm|14|6381|doi:10.1039/c2ce26131f

Space GroupCrystallographyCrystal SystemCrystal Structure4455-Tetramethyl-2-phenyl-45-dihydro-1H-3lambda^5^-imidazole-13-diol 1245-tetrafluoro-36-diiodobenzeneCell ParametersExperimental 3D Coordinates
researchProduct