0000000001313860

AUTHOR

Lindley Maxwell

showing 2 related works from this author

Metal-Organic Nanocapsules with Functionalized s-Heptazine Ligands.

2020

A metalloorganic capsule was synthesized where the ligand is a derivative of heptazine with three carboxylic groups that are coordinated to CuII cations, forming paddle-wheel motifs. Each nanocapsule is neutral, with 12 CuII centers and 8 ligands adopting a rhombicuboctahedron shape. It has almost 3 nm diameter, and the main intermolecular interactions in the solid are π··· π stacking between the C6N7 heptazine moieties. The nanocapsules can form monolayers deposited on graphite as observed by atomic force microscopy, which confirms their stability in solution. peerReviewed

HeptazineNanociènciaLigandorganometalliyhdisteetMoleculesLigandsNanocapsulesInorganic ChemistryMetalchemistry.chemical_compoundNanoscienceLligandschemistryvisual_artPolymer chemistryvisual_art.visual_art_mediumsupramolekulaarinen kemiananohiukkasetPhysical and Theoretical ChemistryMolèculeshuman activitiesDerivative (chemistry)Inorganic chemistry
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CCDC 1951192: Experimental Crystal Structure Determination

2020

Related Article: Lindley Maxwell, Héctor Martínez, Alejandro Martín-Rodríguez, Silvia Gómez-Coca, Kari Rissanen, Eliseo Ruiz|2020|Inorg.Chem.|60|570|doi:10.1021/acs.inorgchem.0c03631

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersoctakis(mu-11'1''-(1346799b-hepta-azaphenalene-258-triyl)tris(piperidine-4-carboxylato))-dodeca-aqua-dodeca-copper dimethyl sulfoxide solvateExperimental 3D Coordinates
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