Author: Lindley Maxwell

0000000001313860

AUTHOR

Lindley Maxwell

Metal-Organic Nanocapsules with Functionalized s-Heptazine Ligands.

A metalloorganic capsule was synthesized where the ligand is a derivative of heptazine with three carboxylic groups that are coordinated to CuII cations, forming paddle-wheel motifs. Each nanocapsule is neutral, with 12 CuII centers and 8 ligands adopting a rhombicuboctahedron shape. It has almost 3 nm diameter, and the main intermolecular interactions in the solid are π··· π stacking between the C6N7 heptazine moieties. The nanocapsules can form monolayers deposited on graphite as observed by atomic force microscopy, which confirms their stability in solution. peerReviewed

research product

CCDC 1951192: Experimental Crystal Structure Determination

Related Article: Lindley Maxwell, Héctor Martínez, Alejandro Martín-Rodríguez, Silvia Gómez-Coca, Kari Rissanen, Eliseo Ruiz|2020|Inorg.Chem.|60|570|doi:10.1021/acs.inorgchem.0c03631

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PEPhysical Sciences and Engineering
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