0000000001313974

AUTHOR

Leonid S. Vlasenko

showing 9 related works from this author

Series of Near-IR-Absorbing Transition Metal Complexes with Redox Active Ligands

2020

New soluble and intensely near-IR-absorbing transition metal (Ti, Zr, V, Ni) complexes were synthesized using a redox non-innocent N,N&rsquo

Spectrometry Mass Electrospray IonizationMagnetic Resonance SpectroscopyElectronsChemistry Techniques SyntheticCrystallography X-RayLigandsArticlelcsh:QD241-441Magneticslcsh:Organic chemistryX-Ray DiffractionCoordination ComplexesNickelTransition Elementsorgaaniset yhdisteetSpectroscopy Near-InfraredMolecular Structureredox-active ligandnon-innocent ligandsElectrochemical Techniquesliganditkompleksiyhdisteetmetal organic complexMetalsElectronicsOxidation-Reduction
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NIR-absorbing transition metal complexes with redox-active ligands

2020

Bench top stable transition metal (M = Co, Ni, Cu) complexes with a non-innocent ortho-aminophenol derivative were synthesized by the reaction of metal(II)acetates with a ligand precursor in 2:1 ratio. The solid-state structures reveal the formation of neutral molecular complexes with square planar coordination geometries. The Co(II) and Cu(II) complexes are paramagnetic, whereas the Ni complex is a diamagnetic square planar low-spin Ni(II) complex. All complexes, and Ni(II) complex in particular, show strong absorption in the near-IR region. Peer reviewed

02 engineering and technologymetal complexesredox-active ligands010402 general chemistry01 natural sciencesInorganic ChemistryMetalParamagnetismchemistry.chemical_compoundTransition metalinfrapunasäteilyMaterials ChemistryPhysical and Theoretical Chemistrynear-IR absorptionChemistryLigandnon-innocent ligandsliganditkompleksiyhdisteet021001 nanoscience & nanotechnologyNon-innocent ligand0104 chemical sciences3. Good healthabsorptioCrystallographyvisual_artvisual_art.visual_art_mediumDiamagnetismAbsorption (chemistry)0210 nano-technologyDerivative (chemistry)
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CCDC 1986213: Experimental Crystal Structure Determination

2021

Related Article: Esko Saloj��rvi, Anssi Peuronen, Manu Lahtinen, Hannu Huhtinen, Leonid S. Vlasenko, Mika Lastusaari, Ari Lehtonen|2020|Molecules|25|2531|doi:10.3390/molecules25112531

Space GroupCrystallographyCrystal SystemCrystal Structurebis{22'-[cyclohexa-35-diene-12-diylidenebis(azanylylidene)]bis(46-di-t-butylphenolato)}-titanium(iv) acetonitrile solvateCell ParametersExperimental 3D Coordinates
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CCDC 1986216: Experimental Crystal Structure Determination

2021

Related Article: Esko Saloj��rvi, Anssi Peuronen, Manu Lahtinen, Hannu Huhtinen, Leonid S. Vlasenko, Mika Lastusaari, Ari Lehtonen|2020|Molecules|25|2531|doi:10.3390/molecules25112531

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(24-di-t-butyl-6-[{6-[(35-di-t-butyl-2-hydroxyphenyl)imino]cyclohexa-24-dien-1-ylidene}amino]phenolato)-{1-[(35-di-t-butyl-2-oxidophenyl)azanidyl]-6-[(35-di-t-butyl-2-oxidophenyl)imino]cyclohexa-24-dien-1-yl radical}-vanadiumExperimental 3D Coordinates
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CCDC 1986214: Experimental Crystal Structure Determination

2021

Related Article: Esko Saloj��rvi, Anssi Peuronen, Manu Lahtinen, Hannu Huhtinen, Leonid S. Vlasenko, Mika Lastusaari, Ari Lehtonen|2020|Molecules|25|2531|doi:10.3390/molecules25112531

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(24-di-t-butyl-6-[{6-[(35-di-t-butyl-2-hydroxyphenyl)imino]cyclohexa-24-dien-1-ylidene}amino]phenolato)-{1-[(35-di-t-butyl-2-oxidophenyl)azanidyl]-6-[(35-di-t-butyl-2-oxidophenyl)imino]cyclohexa-24-dien-1-yl radical}-vanadiumExperimental 3D Coordinates
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CCDC 1986215: Experimental Crystal Structure Determination

2021

Related Article: Esko Saloj��rvi, Anssi Peuronen, Manu Lahtinen, Hannu Huhtinen, Leonid S. Vlasenko, Mika Lastusaari, Ari Lehtonen|2020|Molecules|25|2531|doi:10.3390/molecules25112531

Space GroupCrystallographyCrystal SystemCrystal Structurebis{22'-[cyclohexa-35-diene-12-diylidenebis(azanylylidene)]bis(46-di-t-butylphenolato)}-nickelCell ParametersExperimental 3D Coordinates
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CCDC 1913766: Experimental Crystal Structure Determination

2020

Related Article: Esko Salojärvi, Anssi Peuronen, Hannu Huhtinen, Leonid S. Vlasenko, Janne Halme, Pyry Mäkinen, Mika Lastusaari, Ari Lehtonen|2020|Inorg.Chem.Commun.|112|107711|doi:10.1016/j.inoche.2019.107711

Space GroupCrystallographyCrystal SystemCrystal Structurebis{24-di-t-butyl-6-[(4-nitrophenyl)imino]cyclohexa-24-dien-1-olato radical}-cobalt(ii)Cell ParametersExperimental 3D Coordinates
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CCDC 1913765: Experimental Crystal Structure Determination

2020

Related Article: Esko Salojärvi, Anssi Peuronen, Hannu Huhtinen, Leonid S. Vlasenko, Janne Halme, Pyry Mäkinen, Mika Lastusaari, Ari Lehtonen|2020|Inorg.Chem.Commun.|112|107711|doi:10.1016/j.inoche.2019.107711

Space GroupCrystallographyCrystal SystemCrystal Structurebis{24-di-t-butyl-6-[(4-nitrophenyl)amino]phenolato}-copper(ii)Cell ParametersExperimental 3D Coordinates
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CCDC 1987795: Experimental Crystal Structure Determination

2021

Related Article: Esko Saloj��rvi, Anssi Peuronen, Manu Lahtinen, Hannu Huhtinen, Leonid S. Vlasenko, Mika Lastusaari, Ari Lehtonen|2020|Molecules|25|2531|doi:10.3390/molecules25112531

Space GroupCrystallographybis{22'-[cyclohexa-35-diene-12-diylidenebis(azanylylidene)]bis(46-di-t-butylphenolato)}-zirconium(iv) unknown solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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