0000000001314403
AUTHOR
Mariam Barawi
Hydroxamate Titanium–Organic Frameworks and the Effect of Siderophore-Type Linkers over Their Photocatalytic Activity
The chemistry of metal–organic frameworks (MOFs) relies on the controlled linking of organic molecules and inorganic secondary building units to assemble an unlimited number of reticular frameworks. However, the design of porous solids with chemical stability still remains limited to carboxylate or azolate groups. There is a timely opportunity to develop new synthetic platforms that make use of unexplored metal binding groups to produce metal–linker joints with hydrolytic stability. Living organisms use siderophores (iron carriers in Greek) to effectively assimilate iron in soluble form. These compounds make use of hard oxo donors as hydroxamate or catecholate groups to coordinate metal Lew…
CCDC 1884457: Experimental Crystal Structure Determination
Related Article: Natalia M. Padial, Javier Castells-Gil, Neyvis Almora-Barrios, Mariam Barawi, Ivan da Silva, Víctor A. de la Peña O’Shea and Carlos Martí-Gastaldo|2019|J.Am.Chem.Soc.|141|13124|doi:10.1021/jacs.9b04915