Author: Raphael Marx

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AUTHOR

Raphael Marx

showing 3 related works from this author

Bimetallic MnIII–FeII hybrid complexes formed by a functionalized MnIII Anderson polyoxometalate coordinated to FeII: observation of a field-induced …

2015

The synthesis and crystal structure of an Anderson POM functionalized with two 2,6-di(pyrazol-1-yl)-pyridine (1-bpp) ligands are reported (compound 1). High-frequency electron paramagnetic resonance (HF-EPR) and magnetic measurements show that it presents a significant negative axial zero-field splitting and field-induced slow relaxation of magnetization due to the presence of isolated MnIII anisotropic magnetic ions. Complexation of 1 with FeII gives rise to a 2D cationic network formed by Anderson POMs coordinated to two FeII ions through the two tridentate 1-bpp ligands and to other two FeII ions through two oxo ligands in compound 2, and to an anionic polymeric network formed by Anderso…

Materials scienceStereochemistryRelaxation (NMR)General ChemistryCrystal structureLIESSTlaw.inventionCrystallographyMagnetizationlawSpin crossoverPolyoxometalateMaterials ChemistryMoleculeElectron paramagnetic resonanceJournal of Materials Chemistry C

researchProduct

CCDC 1058520: Experimental Crystal Structure Determination

2015

Related Article: Alexandre Abhervé, Mario Palacios-Corella, Juan Modesto Clemente-Juan, Raphael Marx, Petr Neugebauer, Joris van Slageren, Miguel Clemente-León, Eugenio Coronado|2015|J.Mater.Chem.C|3|7936|doi:10.1039/C5TC01089F

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[bis(mu-N-(13-dioxy-2-(oxymethyl)propan-2-yl)-26-di(1H-pyrazol-1-yl)isonicotinamide)-octakis(mu-oxo)-diaqua-bis(NN-dimethylformamide)-decaoxo-di-iron-manganese-hexa-molybdenum hydroxide NN-dimethylformamide solvate monohydrate]Cell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1058519: Experimental Crystal Structure Determination

2015

Related Article: Alexandre Abhervé, Mario Palacios-Corella, Juan Modesto Clemente-Juan, Raphael Marx, Petr Neugebauer, Joris van Slageren, Miguel Clemente-León, Eugenio Coronado|2015|J.Mater.Chem.C|3|7936|doi:10.1039/C5TC01089F

Space GroupCrystallographyCrystal Systemtris(tetra-n-butylammonium) bis(mu-N-(13-dioxy-2-(oxymethyl)propan-2-yl)-26-di(1H-pyrazol-1-yl)isonicotinamide)-hexakis(mu-oxo)-dodecaoxo-manganese-hexa-molybdenum NN-dimethylacetamide solvate hydrateCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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