0000000001314680

AUTHOR

Vygintas Jankauskas

showing 5 related works from this author

Structure–property relationship of isomeric diphenylethenyl-disubstituted dimethoxycarbazoles

2015

Isomeric 3,6-dimethoxy- and 2,7-dimethoxycarbazoles containing diphenylethenyl moieties were synthesized by condensation of the appropriate dimethoxycarbazoles with diphenylacetaldehyde. The solid-state structures and the molecular order of the compounds were proven by X-ray crystallography. Both compounds were found to be capable of glass formation with comparable glass transition temperatures (70–71 °C). They exhibited high thermal stabilities, with the 5% weight loss temperatures exceeding 375 °C. The isomer having diphenylethenyl groups at C-3 and C-6 positions and methoxy groups at C-2 and C-7 positions (3a) exhibited aggregation-induced emission (AIE), while its counterpart having dip…

Quenching (fluorescence)CarbazoleGeneral Chemical EngineeringGeneral ChemistryFluorescencechemistry.chemical_compoundCrystallographyDipolechemistryComputational chemistryDensity functional theoryGround stateGlass transitionDerivative (chemistry)RSC Advances
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Derivatives of indandione and differently substituted triphenylamine with charge-transporting and NLO properties

2015

Abstract Derivatives containing electron-donaiting triphenylamino groups and electron-withdrawing indandione moieties were synthesized and their thermal, electrochemical, photoelectrical and nonlinear optical properties were studied. The synthesized compounds form glasses with the glass transition temperatures ranging from 69 to 118 °C. The ionization potentials of the solid samples of the synthesized materials were found to be in the range of 5.48–5.69 eV. Hole-drift mobilities estimated by xerographic time of flight technique in the amorphous layers of 2-({4-[(4-{[(2E)-1,3-dioxo-2,3-dihydro-1H-inden-2-ylidene]methyl}phenyl)(4-methoxyphenyl)amino]phenyl}methylidene)-2,3-dihydro-1H-indene-1…

Materials scienceProcess Chemistry and TechnologyGeneral Chemical EngineeringCharge (physics)ElectrochemistryTriphenylamineAmorphous solidchemistry.chemical_compoundchemistryElectric fieldIonizationPhysical chemistryOrganic chemistryIonization energyGlass transitionDyes and Pigments
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Enamine-based hole transporting materials for vacuum-deposited perovskite solar cells

2020

In a short period of time, the rapid development of perovskite solar cells attracted a lot of attention in the science community with the record for power conversion efficiency being broken every year. Despite the fast progress in power conversion efficiency there are still many issues that need to be solved before starting large scale commercial applications, such as, among others, the difficult and costly synthesis and usage of toxic solvents for the deposition of hole transport materials (HTMs). We herein report new enamine-based charge transport materials obtained via a simple one step synthesis procedure, from commercially available precursors and without the use of expensive organomet…

Materials scienceenamine-based hole transporting materialsEnergy Engineering and Power Technology02 engineering and technology010402 general chemistry01 natural sciences7. Clean energyperovskite solar cellsCatalysisEnaminechemistry.chemical_compoundVacuum depositionElectric fieldDeposition (phase transition)Materialsenamine-based hole transporting materials ; vacuum-deposited ; perovskite solar cellsCèl·lules fotoelèctriquesPerovskite (structure)Renewable Energy Sustainability and the Environmentbusiness.industryEnergy conversion efficiency021001 nanoscience & nanotechnology0104 chemical sciencesThermogravimetryFuel TechnologychemistryOptoelectronics0210 nano-technologybusinessvacuum-deposited
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CCDC 1042467: Experimental Crystal Structure Determination

2015

Related Article: Audrius Bucinskas, Gintautas Bagdziunas, Ausra Tomkeviciene, Dmytro Volynyuk, Nataliya Kostiv, Dalius Gudeika, Vygintas Jankauskas, Martins Rutkis, Juozas V. Grazulevicius|2015|RSC Advances|5|49577|doi:10.1039/C5RA09161F

Space GroupCrystallographyCrystal SystemCrystal Structure36-bis(22-Diphenylvinyl)-9-(2-ethylhexyl)-27-dimethoxy-9H-carbazoleCell ParametersExperimental 3D Coordinates
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CCDC 1042468: Experimental Crystal Structure Determination

2015

Related Article: Audrius Bucinskas, Gintautas Bagdziunas, Ausra Tomkeviciene, Dmytro Volynyuk, Nataliya Kostiv, Dalius Gudeika, Vygintas Jankauskas, Martins Rutkis, Juozas V. Grazulevicius|2015|RSC Advances|5|49577|doi:10.1039/C5RA09161F

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates27-bis(22-Diphenylvinyl)-9-(2-ethylhexyl)-36-dimethoxy-9H-carbazole methanol solvate
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