0000000001315224

AUTHOR

Andrew Ozarowski

showing 4 related works from this author

Dinuclear manganese(iii) complexes with bioinspired coordination and variable linkers showing weak exchange effects: a synthetic, structural, spectro…

2019

Three dimanganese(iii) complexes have been synthesised and fully characterised by standard spectroscopic methods and spectroelectrochemistry. Each MnIII ion is chelated by a salen type ligand (H2L), but there is variation in the bridging group: LMn(OOCCH[double bond, length as m-dash]CHCOO)MnL, LMn(OOCC6H4COO)MnL, and LMn(OOCC6H4C6H4COO)MnL. X-ray diffraction revealed an axial compression of each six-coordinate high-spin d4 MnIII ion, which is a Jahn-Teller-active ion. Temperature dependent magnetic susceptibility and variable temperature-variable field (VTVH) magnetisation measurements, as well as high-frequency and -field EPR (HFEPR) spectroscopy were used to accurately describe the magne…

Materials scienceAbsorption spectroscopy010405 organic chemistryExchange interactionchemistry.chemical_elementManganese010402 general chemistry01 natural sciencesMagnetic susceptibility0104 chemical scienceslaw.inventionIonInorganic ChemistryCrystallographyMagnetizationchemistrylawElectron paramagnetic resonanceSpectroscopyDalton Transactions
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CCDC 1875357: Experimental Crystal Structure Determination

2019

Related Article: Sergiu Shova, Angelica Vlad, Maria Cazacu, J. Krzystek, Andrew Ozarowski, Michal Malček, Lukas Bucinsky, Peter Rapta, Joan Cano, Joshua Telser, Vladimir B. Arion|2019|Dalton Trans.|48|5909|doi:10.1039/C8DT04596H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-(11'-biphenyl)-44'-dicarboxylato)-bis(22'-{(1133-tetramethyldisiloxane-13-diyl)bis[(propane-31-diyl)azanylidenemethanylidene]}bis(46-di-t-butylphenolato))-di-manganese(iii) hydrateExperimental 3D Coordinates
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CCDC 1875359: Experimental Crystal Structure Determination

2019

Related Article: Sergiu Shova, Angelica Vlad, Maria Cazacu, J. Krzystek, Andrew Ozarowski, Michal Malček, Lukas Bucinsky, Peter Rapta, Joan Cano, Joshua Telser, Vladimir B. Arion|2019|Dalton Trans.|48|5909|doi:10.1039/C8DT04596H

Space GroupCrystallographyCrystal System(mu-but-2-enedioato)-bis(22'-{(1133-tetramethyldisiloxane-13-diyl)bis[(propane-31-diyl)azanylidenemethanylidene]}bis(46-di-t-butylphenolato))-di-manganese(iii) dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1875358: Experimental Crystal Structure Determination

2019

Related Article: Sergiu Shova, Angelica Vlad, Maria Cazacu, J. Krzystek, Andrew Ozarowski, Michal Malček, Lukas Bucinsky, Peter Rapta, Joan Cano, Joshua Telser, Vladimir B. Arion|2019|Dalton Trans.|48|5909|doi:10.1039/C8DT04596H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-benzene-14-dicarboxylato)-bis(22'-{(1133-tetramethyldisiloxane-13-diyl)bis[(propane-31-diyl)azanylidenemethanylidene]}bis(46-di-t-butylphenolato))-di-manganese(iii) dichloromethane solvateExperimental 3D Coordinates
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