0000000001315475
AUTHOR
N. Marchini
The GALILEO γ-ray array at the Legnaro National Laboratories
Abstract GALILEO, a new 4 π high-resolution γ -detection array, based on HPGe detectors, has been developed and installed at the Legnaro National Laboratories. The GALILEO array greatly benefits from a fully-digital read-out chain, customized DAQ, and a variety of complementary detectors to improve the resolving power by the detection of particles, ions or high-energy γ -ray transitions. In this work, a full description of the array, including electronics and DAQ, is presented together with its complementary instrumentation.
Synthesis and X-ray crystal structure of cationic polynuclear hydroxide acetylacetonate lanthanide(III) clusters with homodinuclear or heterodinuclear decacarbonyl hydrides: [HMo2(CO)10]− and [HCrW(CO)10]−
The synthesis and characterization of new polynuclear lanthanide(III) ionic clusters of general formula [Ln 9 (acac) 16 (OH) 10 ] + [Mo 2 (CO) 10 (μ-H)]- (Ln = Sm, Eu, Gd, Dy, Yb) and [Sm 9 (acac) 16 OH) 10 ] + [CrW(CO) 10 (μ-H)] - is reported. The polynuclear complexes, prepared under pure nitrogen atmosphere by interaction of the hydridic metal carbonyls with the β-dichetonate Ln(acac) 3 ·3H 2 O (Ln=Sm, Eu, Gd, Dy, Yb). The new clusters were characterized by elemental analysis, complexometric titration for Ln, atomic absorption for Cr, W and Mo, gas-volumetric analysis for CO, FTIR spectroscopy and single crystal X-ray structure determination of [Sm 9 (acac) 16 (OH) 10 ][Mo 2 (CO) 10 (μ-H…
CCDC 254789: Experimental Crystal Structure Determination
Related Article: M.Volpe, G.Bombieri, N.Marchini|2006|J.Alloys Compd.|408|1046|doi:10.1016/j.jallcom.2004.12.132
CCDC 275693: Experimental Crystal Structure Determination
Related Article: G.Daidone, B.Maggio, M.V.Raimondi, G.Bombieri, N.Marchini, R.Artali|2005|Heterocycles|65|2753|doi:10.3987/COM-05-10499
CCDC 275436: Experimental Crystal Structure Determination
Related Article: G.Daidone, B.Maggio, M.V.Raimondi, G.Bombieri, N.Marchini, R.Artali|2005|Heterocycles|65|2753|doi:10.3987/COM-05-10499