0000000001315520

AUTHOR

Rochel M. Lago

showing 5 related works from this author

Surface properties and catalytic performance for ethane combustion of La1−xKxMnO3+δ perovskites

2001

Abstract The influence of K substitution in LaMnO3 perovskite on the surface properties and catalytic oxidation of ethane has been studied. La1−xKxMnO3+δ perovskites (x=0.05, 0.10, 0.15, 0.20 and 0.25) with BET surface area of 20–26 m2 g−1 have been prepared by the freeze-drying method and characterized by X-ray diffraction patterns (XRD), TPR, TPD and XPS. The XRD analyses showed the presence of a single crystalline phase (x≤0.15) with the linear increase of the lattice parameter corroborating the incorporation of potassium in the perovskite structure. The XPS studies revealed an enrichment of the perovskite surface with potassium accompanied by an increase in the surface Mn4+/Mn3+ ratio. …

Thermal desorption spectroscopyProcess Chemistry and TechnologyInorganic chemistrychemistry.chemical_elementOxygenCatalysisPotassium oxideCatalysischemistry.chemical_compoundCatalytic oxidationchemistryDesorptionPerovskite (structure)BET theoryApplied Catalysis A: General
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A pH-triggered bistable copper(II) metallacycle as a reversible emulsion switch for biphasic processes.

2013

A unique bistable copper-metallacyclic complex is used as an elegant molecular switch for the reversible formation of emulsions by simple pH variation. This switch may have several exciting applications in biphasic processes such as catalysis and separation science technologies.

Molecular switchBistabilityChemistryMetals and Alloyschemistry.chemical_elementGeneral ChemistryMetallacyclePhotochemistryCopperCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysisEmulsionMaterials ChemistryCeramics and CompositesPh triggeredChemical communications (Cambridge, England)
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CCDC 927505: Experimental Crystal Structure Determination

2013

Related Article: Walace D. do Pim, Willian X. C. Oliveira, Marcos A. Ribeiro, Érica N. de Faria, Ivo F. Teixeira, Humberto O. Stumpf, Rochel M. Lago, Cynthia L. M. Pereira, Carlos B. Pinheiro, João C. D. Figueiredo-Júnior, Wallace C. Nunes, Patterson P. de Souza, Emerson F. Pedroso, María Castellano, Joan Cano, Miguel Julve|2013|Chem.Commun.|49|10778|doi:10.1039/C3CC46242K

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu2-22'-(Ethane-12-diylbis(21-phenyleneimino))bis((oxo)acetato))-bis(ethanol)-di-copper(ii) ethanol solvateExperimental 3D Coordinates
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CCDC 927507: Experimental Crystal Structure Determination

2013

Related Article: Walace D. do Pim, Willian X. C. Oliveira, Marcos A. Ribeiro, Érica N. de Faria, Ivo F. Teixeira, Humberto O. Stumpf, Rochel M. Lago, Cynthia L. M. Pereira, Carlos B. Pinheiro, João C. D. Figueiredo-Júnior, Wallace C. Nunes, Patterson P. de Souza, Emerson F. Pedroso, María Castellano, Joan Cano, Miguel Julve|2013|Chem.Commun.|49|10778|doi:10.1039/C3CC46242K

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatestetrakis(tetra-n-butylammonium) Bis(mu2-(((2-(2-(2-(((carboxy)carbonyl)amino)phenyl)ethyl)phenyl)amino)(oxo)acetato))-di-copper(ii) tetrahydrate
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CCDC 927506: Experimental Crystal Structure Determination

2013

Related Article: Walace D. do Pim, Willian X. C. Oliveira, Marcos A. Ribeiro, Érica N. de Faria, Ivo F. Teixeira, Humberto O. Stumpf, Rochel M. Lago, Cynthia L. M. Pereira, Carlos B. Pinheiro, João C. D. Figueiredo-Júnior, Wallace C. Nunes, Patterson P. de Souza, Emerson F. Pedroso, María Castellano, Joan Cano, Miguel Julve|2013|Chem.Commun.|49|10778|doi:10.1039/C3CC46242K

Space GroupCrystallographyCrystal SystemDiethyl 22'-(ethane-12-diylbis(21-phenyleneimino))bis(oxoacetate)Crystal StructureCell ParametersExperimental 3D Coordinates
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