0000000001315523
AUTHOR
María José Recio-carretero
Nonanuclear Spin-Crossover Complex Containing Iron(II) and Iron(III) Based on a 2,6-Bis(pyrazol-1-yl)pyridine Ligand Functionalized with a Carboxylate Group.
The synthesis and magnetostructural characterization of [Fe(III)3(μ3-O)(H2O)3[Fe(II)(bppCOOH)(bppCOO)]6](ClO4)13·(CH3)2CO)6·(solvate) (2) are reported. This compound is obtained as a secondary product during synthesis of the mononuclear complex [Fe(II)(bppCOOH)2](ClO4)2 (1). The single-crystal X-ray diffraction structure of 2 shows that it contains the nonanuclear cluster of the formula [Fe(III)3(μ3-O)(H2O)3[Fe(II)(bppCOOH)(bppCOO)]6](13+), which is formed by a central Fe(III)3O core coordinated to six partially deprotonated [Fe(II)(bppCOOH)(bppCOO)](+) complexes. Raman spectroscopy studies on single crystals of 1 and 2 have been performed to elucidate the spin and oxidation states of iron …
CCDC 1486674: Experimental Crystal Structure Determination
Related Article: Alexandre Abhervé, María José Recio-Carretero, Maurici López-Jordà, Juan Modesto Clemente-Juan, Josep Canet-Ferrer, Andrés Cantarero, Miguel Clemente-León, and Eugenio Coronado|2016|Inorg.Chem.|55|9361|doi:10.1021/acs.inorgchem.6b01508
CCDC 1486675: Experimental Crystal Structure Determination
Related Article: Alexandre Abhervé, María José Recio-Carretero, Maurici López-Jordà, Juan Modesto Clemente-Juan, Josep Canet-Ferrer, Andrés Cantarero, Miguel Clemente-León, and Eugenio Coronado|2016|Inorg.Chem.|55|9361|doi:10.1021/acs.inorgchem.6b01508