0000000001315805
AUTHOR
Charles E. Schulz
Synthesis, UV/vis, FT-IR and Mössbauer spectroscopic characterization and molecular structure of the Bis[4-(2-aminoethyl)morpholine](tetrakis(4-metoxyphenyl)porphyrinato) iron(II) complex
International audience; The synthesis, the UV-visible, FT-IR and Mossbauer spectroscopy and the crystal structure characterizations of the bis[4-(2-Aminoethyl)morpholine]tetrakis(4-metoxyphenyl)porphy-rinato)iron(II) complex are described. The title compound crystallizes in the triclinic, space group P-1, with a = 11.1253(4) angstrom, b = 11.2379(4) angstrom, c = 11.5488(4) angstrom, alpha = 72.304(2)degrees, beta = 86.002(2)degrees gamma = 72.066(2)degrees, V = 1308.28(8) angstrom(3), Z = 1. The Mossbauer data are consistent with an iron(II) low-spin (S = 0) porphyin species. The spin-state is confirmed by the value of the average equatorial iron-nitrogen pyrrole distance (Fe-Np = 1.988(2)…
New insights on the electronic, magnetic, electric and molecular structure of a bis-(4-cyanopyridine) iron(III) complex with the meso-tetrakis(4-methoxyphenyl)porphyrin
International audience; We have successfully synthesized and characterized a new low-spin iron(III) bis(4-cyanopyridine) complex with a meso-porphyrin substituted in the para positions of the phenyls by the methoxy group, namely the bis(4-cyanopyridine)[(meso-tetrakis(4-metoxyphenylporphyrinato)]iron(III) trifluoromethanesulfonate chlorobenzene monosolvate complex with the formula [FeIII(TMPP)(4-CNpy)2]SO3CF3.C6H5Cl (I). This species was characterized through ultraviolet–visible, Fourier-transform infrared and Mössbauer spectroscopy as well as by SQUID magnetometry, cyclic voltammetry, and X-ray crystallography. These characterizations indicated that our synthetic heme model is a low-spin (…
CCDC 976071: Experimental Crystal Structure Determination
Related Article: Arbia Ben Khélifa, Khaireddine Ezzayani, Mouhamed Salah Belkhiria|2016|J.Mol.Struct.|1122|18|doi:10.1016/j.molstruc.2016.05.067
CCDC 975958: Experimental Crystal Structure Determination
Related Article: Leila Ben Haj Hassen, Selma Dhifaoui, Yoann Rousselin, Valérie Marvaud, Christine Stern, Charles E. Schulz, Habib Nasri|2019|Inorg.Chim.Acta|486|675|doi:10.1016/j.ica.2018.11.040