0000000001315805

AUTHOR

Charles E. Schulz

showing 4 related works from this author

Synthesis, UV/vis, FT-IR and Mössbauer spectroscopic characterization and molecular structure of the Bis[4-(2-aminoethyl)morpholine](tetrakis(4-metox…

2016

International audience; The synthesis, the UV-visible, FT-IR and Mossbauer spectroscopy and the crystal structure characterizations of the bis[4-(2-Aminoethyl)morpholine]tetrakis(4-metoxyphenyl)porphy-rinato)iron(II) complex are described. The title compound crystallizes in the triclinic, space group P-1, with a = 11.1253(4) angstrom, b = 11.2379(4) angstrom, c = 11.5488(4) angstrom, alpha = 72.304(2)degrees, beta = 86.002(2)degrees gamma = 72.066(2)degrees, V = 1308.28(8) angstrom(3), Z = 1. The Mossbauer data are consistent with an iron(II) low-spin (S = 0) porphyin species. The spin-state is confirmed by the value of the average equatorial iron-nitrogen pyrrole distance (Fe-Np = 1.988(2)…

Supramolecular chemistry02 engineering and technologyCrystal structureTriclinic crystal system010402 general chemistryspin01 natural sciencesUV-visible[ CHIM ] Chemical SciencesAnalytical ChemistryInorganic ChemistryMossbauerchemistry.chemical_compoundMorpholineMössbauer spectroscopy[CHIM]Chemical SciencesSpectroscopyPyrroleHydrogen bondOrganic Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesX-ray diffractionCrystallographychemistryIron porphyrin complexX-ray crystallography0210 nano-technologycrystal-structures
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New insights on the electronic, magnetic, electric and molecular structure of a bis-(4-cyanopyridine) iron(III) complex with the meso-tetrakis(4-meth…

2019

International audience; We have successfully synthesized and characterized a new low-spin iron(III) bis(4-cyanopyridine) complex with a meso-porphyrin substituted in the para positions of the phenyls by the methoxy group, namely the bis(4-cyanopyridine)[(meso-tetrakis(4-metoxyphenylporphyrinato)]iron(III) trifluoromethanesulfonate chlorobenzene monosolvate complex with the formula [FeIII(TMPP)(4-CNpy)2]SO3CF3.C6H5Cl (I). This species was characterized through ultraviolet–visible, Fourier-transform infrared and Mössbauer spectroscopy as well as by SQUID magnetometry, cyclic voltammetry, and X-ray crystallography. These characterizations indicated that our synthetic heme model is a low-spin (…

Cyclic voltammetryInfrared010402 general chemistry01 natural sciencesCoordination complexInorganic Chemistrychemistry.chemical_compoundMagnetic propertiesMössbauer spectroscopy[CHIM.CRIS]Chemical Sciences/CristallographyMaterials ChemistryMolecule[CHIM.COOR]Chemical Sciences/Coordination chemistryPhysical and Theoretical ChemistryX-ray Molecular structureHemechemistry.chemical_classification010405 organic chemistryChemistryIron(III) porphyrin0104 chemical sciences3. Good healthCrystallographyChlorobenzeneCyclic voltammetryTrifluoromethanesulfonateInorganica Chimica Acta
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CCDC 976071: Experimental Crystal Structure Determination

2016

Related Article: Arbia Ben Khélifa, Khaireddine Ezzayani, Mouhamed Salah Belkhiria|2016|J.Mol.Struct.|1122|18|doi:10.1016/j.molstruc.2016.05.067

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesbis(2-(morpholin-4-yl)ethanamine)-(5101520-tetrakis(4-methoxyphenyl)porphyrinato)-iron(ii)
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CCDC 975958: Experimental Crystal Structure Determination

2019

Related Article: Leila Ben Haj Hassen, Selma Dhifaoui, Yoann Rousselin, Valérie Marvaud, Christine Stern, Charles E. Schulz, Habib Nasri|2019|Inorg.Chim.Acta|486|675|doi:10.1016/j.ica.2018.11.040

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(isonicotinonitrile)-(5101520-tetrakis(4-methoxyphenyl)porphyrinato)-iron(iii) trifluoromethanesulfonate chlorobenzene solvateExperimental 3D Coordinates
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