0000000001315812
AUTHOR
Thomas Pickl
Boron–nitrogen substituted dihydroindeno[1,2-b]fluorene derivatives as acceptors in organic solar cells
The electrophilic borylation of 2,5-diarylpyrazines results in the formation of boron–nitrogen doped dihydroindeno[1,2-b]fluorene which can be synthesized using standard Schlenk techniques and worked up and handled readily under atmospheric conditions. Through transmetallation via diarylzinc reagents a series of derivatives were synthesized which show broad visible to near-IR light absorption profiles that highlight the versatility of this BN substituted core for use in optoelectronic devices. The synthesis is efficient, scalable and allows for tuning through changes in substituents on the planar heterocyclic core and at boron. Exploratory evaluation in organic solar cell devices as non-ful…
CCDC 1937170: Experimental Crystal Structure Determination
Related Article: Matthew M. Morgan, Maryam Nazari, Thomas Pickl, J. Mikko Rautiainen, Heikki M. Tuononen, Warren E. Piers, Gregory C. Welch, Benjamin S. Gelfand|2019|Chem.Commun.|55|11095|doi:10.1039/C9CC05103A
CCDC 1937169: Experimental Crystal Structure Determination
Related Article: Matthew M. Morgan, Maryam Nazari, Thomas Pickl, J. Mikko Rautiainen, Heikki M. Tuononen, Warren E. Piers, Gregory C. Welch, Benjamin S. Gelfand|2019|Chem.Commun.|55|11095|doi:10.1039/C9CC05103A