0000000001316020
AUTHOR
Olivier Alévêque
Controlling the Host-Guest Interaction Mode through a Redox Stimulus
International audience; A proof-of-concept related to the redox-control of the binding/releasing process in a host-guest system is achieved by designing a neutral and robust Pt-based redox-active metallacage involving two extended-tetrathiafulvalene (exTTF) ligands. When neutral, the cage is able to bind a planar polyaromatic guest (coronene). Remarkably, the chemical or electrochemical oxidation of the host-guest complex leads to the reversible expulsion of the guest outside the cavity, which is assigned to a drastic change of the host-guest interaction mode, illustrating the key role of counteranions along the exchange process. The reversible process is supported by various experimental d…
CCDC 1562676: Experimental Crystal Structure Determination
Related Article: György Szalóki, Vincent Croué, Vincent Carré, Frédéric Aubriet, Olivier Alévêque, Eric Levillain, Magali Allain, Juan Aragó, Enrique Ortí, Sébastien Goeb, Marc Sallé|2017|Angew.Chem.,Int.Ed.|56|16272|doi:10.1002/anie.201709483
CCDC 1562675: Experimental Crystal Structure Determination
Related Article: György Szalóki, Vincent Croué, Vincent Carré, Frédéric Aubriet, Olivier Alévêque, Eric Levillain, Magali Allain, Juan Aragó, Enrique Ortí, Sébastien Goeb, Marc Sallé|2017|Angew.Chem.,Int.Ed.|56|16272|doi:10.1002/anie.201709483