0000000001316362
AUTHOR
Qihao Zhu
showing 4 related works from this author
Interactions of a Diplumbyne with Dinuclear Transition Metal Carbonyls to Afford Metalloplumbylenes
2020
The metathesis reactions of the diplumbyne AriPr6PbPbAriPr6 (AriPr6 = −C6H3–2,6-(C6H2–2,4,6-iPr3)2) with the dinuclear metal carbonyls Mn2(CO)10, Fe2(CO)9, and Co2(CO)8 under mild conditions afforded the complexes Mn(CO)5(PbAriPr6) (1), Fe(CO)4(PbAriPr6)2 (2), and Co4(CO)9(PbAriPr6)2 (3), respectively. Complexes 1–3 were structurally characterized by single-crystal X-ray diffraction and spectroscopically characterized by 1H, 13C{1H}, 59Co{1H}, and 207Pb{1H} NMR; UV–vis; and IR methods. They are rare examples of species formed by the direct reaction of a group 14 dimetallyne with transition metal carbonyls. Complexes 1 and 2 feature Mn–Pb or Fe–Pb single bonds, whereas in 3 a Co–Pb cluster i…
CCDC 2027035: Experimental Crystal Structure Determination
2020
Related Article: Qihao Zhu, James C. Fettinger, Petra Vasko, Philip P. Power|2020|Organometallics|39|4629|doi:10.1021/acs.organomet.0c00659
CCDC 2018925: Experimental Crystal Structure Determination
2020
Related Article: Qihao Zhu, James C. Fettinger, Petra Vasko, Philip P. Power|2020|Organometallics|39|4629|doi:10.1021/acs.organomet.0c00659
CCDC 2018923: Experimental Crystal Structure Determination
2020
Related Article: Qihao Zhu, James C. Fettinger, Petra Vasko, Philip P. Power|2020|Organometallics|39|4629|doi:10.1021/acs.organomet.0c00659