0000000001316364

AUTHOR

Lisa Suntrup

showing 3 related works from this author

An aryl-fused redox-active tetrathiafulvalene with enhanced mixed-valence and radical-cation dimer stabilities.

2018

Molecular recognition of stable organic radicals is a relatively novel, but important structural binding motif in supramolecular chemistry. Here, we report on a redox-switchable veratrole-fused tetrathiafulvalene derivative VTTF which is ideally suited for this purpose and for the incorporation into stimuli-responsive systems. As revealed by electrochemistry, UV/Vis measurements, X-ray analysis, and electrocrystallisation, VTTF can be reversibly oxidised to the corresponding radical-cation or dication which shows optoelectronic and structural propterties similar to tetrathiafulvalene and tetrakis(methylthio)tetrathiafulvalene. However, theoretical calculations, variable temperature EPR, and…

010405 organic chemistryChemistryArylDimerRadicalOrganic ChemistrySupramolecular chemistry010402 general chemistry01 natural sciencesBiochemistrysupramolecular chemistry0104 chemical scienceslaw.inventionDicationchemistry.chemical_compoundCrystallographyRadical ionlawsupramolekulaarinen kemiaPhysical and Theoretical ChemistryElectron paramagnetic resonanceta116TetrathiafulvaleneOrganicbiomolecular chemistry
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CCDC 1581480: Experimental Crystal Structure Determination

2018

Related Article: Hendrik V. Schröder, Felix Witte, Marius Gaedke, Sebastian Sobottka, Lisa Suntrup, Henrik Hupatz, Arto Valkonen, Beate Paulus, Kari Rissanen, Biprajit Sarkar, Christoph A. Schalley|2018|Org.Biomol.Chem.|16|2741|doi:10.1039/C8OB00415C

2-(67-dimethoxy-2H-[13]dithiolo[45-b][14]benzodithiin-2-ylidene)-45-bis(methylsulfanyl)-2H-13-dithiole-13-diium bis(tetrafluoroborate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1586984: Experimental Crystal Structure Determination

2018

Related Article: Hendrik V. Schröder, Felix Witte, Marius Gaedke, Sebastian Sobottka, Lisa Suntrup, Henrik Hupatz, Arto Valkonen, Beate Paulus, Kari Rissanen, Biprajit Sarkar, Christoph A. Schalley|2018|Org.Biomol.Chem.|16|2741|doi:10.1039/C8OB00415C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2-[45-bis(methylsulfanyl)-2H-13-dithiol-2-ylidene]-67-dimethoxy-2H-[13]dithiolo[45-b][14]benzodithiineExperimental 3D Coordinates
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