Author: Mahsa Khorshidifard

0000000001316444

AUTHOR

Mahsa Khorshidifard

showing 3 related works from this author

Effects of electron donating/withdrawing groups in the 5-substituted-2-hydroxybenzaldehyde on the synthesis of neutral cubanes with a NiII4O4core: sy…

2016

Two tetranuclear cubane-like nickel(II) complexes of formula [Ni4(CH3O)4(L1)4(CH3OH)4] (1) and [Ni4(CH3O)4(L2)4(CH3OH)4] (2) (HL1 = 2-hydroxybenzaldehyde and HL2 = 2-hydroxy-5-methylbenzaldehyde) have been prepared by the reaction of NiCl2·6H2O with methanolic solutions of HL1 and HL2 in the presence of triethylamine at room temperature. Complexes 1 and 2 have been characterized by elemental analyses, IR spectra and single-crystal X-ray diffraction. The X-ray crystal structure analysis revealed that 1 and 2 have a cubane-type structural topology with four Ni(II) ions and four methoxo-oxygen atoms regularly alternating at the corners. Each metal ion in 1 and 2 is six-coordinate in a distorte…

Denticity010405 organic chemistryStereochemistryGeneral Chemical EngineeringChemistry (all)Intermolecular forceGeneral ChemistryCrystal structure010402 general chemistry01 natural sciences0104 chemical scienceschemistry.chemical_compoundCrystallographychemistryFerromagnetismCubaneOctahedral molecular geometryMoleculeAntiferromagnetismChemical Engineering (all)Chemistry (all); Chemical Engineering (all)RSC Advances

researchProduct

CCDC 1440699: Experimental Crystal Structure Determination

2016

Related Article: Hadi Amiri Rudbari, Francisco Lloret, Mahsa Khorshidifard, Giuseppe Bruno, Miguel Julve|2016|RSC Advances|6|7189|doi:10.1039/C5RA25969J

Space GroupCrystallographytetrakis(mu3-methoxo)-tetrakis(2-formyl-4-methylphenolato)-tetrakis(methanol)-tetra-nickel(ii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1440698: Experimental Crystal Structure Determination

2016

Related Article: Hadi Amiri Rudbari, Francisco Lloret, Mahsa Khorshidifard, Giuseppe Bruno, Miguel Julve|2016|RSC Advances|6|7189|doi:10.1039/C5RA25969J

Space GroupCrystallographyCrystal SystemCrystal Structuretetrakis(mu3-Methoxo)-tetrakis(methanol)-tetrakis(salicylaldehydato)-tetra-nickelCell ParametersExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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