0000000001316454

AUTHOR

Changchun Liu

showing 2 related works from this author

Dimerization control in the self-assembly behavior of copillar[5]arenes bearing ω-hydroxyalkoxy groups.

2012

Two novel copillar[5]arenes bearing ω-hydroxyalkoxy groups are synthesized and their self-assembly properties are studied by (1)H NMR spectroscopy, specific viscosity, and X-ray measurements. The copillar[5]arene 2b bearing a 6-hydroxyhexyloxy group exhibits a reversible self-assembly behavior, leading to the formation of the self-inclusion monomer and hugging dimers. The reversible self-assembly behavior can be controlled by tuning solvent, temperature, guest, and H-bond interaction. However, the copillar[5]arene 2a bearing a short 4-hydroxybutyloxy group does not show such a self-assembly behavior to the formation of the self-inclusion monomer and hugging dimers.

Bridged-Ring CompoundsModels Molecular1h nmr spectroscopyBearing (mechanical)Molecular StructureIntrinsic viscosityOrganic ChemistryPhotochemistrylaw.inventionSolventCrystallographychemistry.chemical_compoundMonomerchemistryGroup (periodic table)lawAlcoholsBenzene DerivativesDimerizationThe Journal of organic chemistry
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CCDC 882877: Experimental Crystal Structure Determination

2013

Related Article: Luzhi Liu, Lingyun Wang, Changchun Liu, Zhiyong Fu, Herbert Meier, and Derong Cao|2012|J.Org.Chem.|77|9413|doi:10.1021/jo301779y

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters6-((91419242628303234-Nonamethoxyhexacyclo[21.2.2.2^36^.2^811^.2^1316^.2^1821^]pentatriaconta-1(25)3581013151820232628303234-pentadecaen-4-yl)oxy)hexa-135-trien-1-ol chloroform solvateExperimental 3D Coordinates
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