0000000001316495

AUTHOR

Jens Dittmer

showing 2 related works from this author

Porous Coordination Polymer Based on Bipyridinium Carboxylate Linkers with High and Reversible Ammonia Uptake

2016

The zwitterionic bipyridinium carboxylate ligand 1,1'-bis(4-carboxyphenyl)-4,4'-bipyridinium (pc1) in the presence of cadmium chloride affords novel porous coordination polymers (PCPs): [Cd4(pc1)3Cl6]·CdCl4·guest (1) crystallizing in the P3̅1c space group. In the structure, [Cd4Cl6(CO2)6] building units are linked together by six pc1 ligands, leading to a 3D high-symmetrical network exhibiting hexagonal channels along the c axis. The walls of this PCP consist of cationic electron-acceptor bipyridinium units. The PCP 1 reversibly adsorbs H2O and CH3OH up to about 0.1 g/g at saturation showing the adsorption isotherms characteristic of a moderately hydrophilic sorbent. Adsorption of ammonia (…

SorbentCoordination polymerLigandInorganic chemistryCationic polymerization02 engineering and technologyCrystal structureCadmium chloride010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences3. Good health0104 chemical sciencesInorganic Chemistry[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistrychemistry.chemical_compoundAdsorptionchemistryPolymer chemistry[CHIM]Chemical SciencesCarboxylatePhysical and Theoretical Chemistry0210 nano-technologyComputingMilieux_MISCELLANEOUS
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CCDC 1473082: Experimental Crystal Structure Determination

2016

Related Article: Maxime Leroux, Nicolas Mercier, Magali Allain, Marie-Claire Dul, Jens Dittmer, Abdel Hadi Kassiba, Jean-Pierre Bellat, Guy Weber, and Igor Bezverkhyy|2016|Inorg.Chem.|55|8587|doi:10.1021/acs.inorgchem.6b01119

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tris(mu-NN'-bis(4-carboxylatophenyl)-44'-bipyridinium)-hexakis(mu-chloro)-tetra-cadmium tetrachloro-cadmium octahydrate)Experimental 3D Coordinates
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