0000000001317082
AUTHOR
Wojciech Czardybon
Synthesis, characterization and solid-state photoluminescence studies of six alkoxy phenylene ethynylene dinuclear palladium(II) rods
A rare family of six discrete binuclear [PdCl(PEt3)2] phenylene ethynylene rods with alkoxy side chains (methoxy, ethoxy and heptoxy) have been developed, and their solid-state photoluminescence results have been presented and discussed. The shorter bridging ligands are of the general formula H–CuC– C6H2(R)2–CuC–H, where R = H, OCH3, OC 2H5, and OC7H15, whereas the longer ones are based on H– CuC–C6H4–CuC–C6H2(R)2–CuC–C6H4–CuC–H, where R = OCH3, OC 2H5. These ligands display increasing length in both the main dimension (backbone length) as well as the number of carbons in the side chains (R, alkoxide side chain) that stem from the central phenylene moiety. The X-ray crystal structures of tw…
CCDC 882325: Experimental Crystal Structure Determination
Related Article: João Figueira, Wojciech Czardybon, José Carlos Mesquita, João Rodrigues, Fernando Lahoz, Luca Russo, Arto Valkonen, Kari Rissanen|2015|Dalton Trans.|44|4003|doi:10.1039/C4DT00493K
CCDC 882324: Experimental Crystal Structure Determination
Related Article: João Figueira, Wojciech Czardybon, José Carlos Mesquita, João Rodrigues, Fernando Lahoz, Luca Russo, Arto Valkonen, Kari Rissanen|2015|Dalton Trans.|44|4003|doi:10.1039/C4DT00493K