0000000001317138

AUTHOR

Paul C. J. Kamer

showing 19 related works from this author

Wide-Bite-Angle Diphosphine Ligands in Thermally Activated Delayed Fluorescent Copper(I) Complexes: Impact on the Performance of Electroluminescence …

2021

We report a series of seven cationic heteroleptic copper(I) complexes of the form [Cu(P^P)(dmphen)]BF4, where dmphen is 2,9-dimethyl-1,10-phenanthroline and P^P is a diphosphine chelate, in which the effect of the bite angle of the diphosphine ligand on the photophysical properties of the complexes was studied. Several of the complexes exhibit moderately high photoluminescence quantum yields in the solid state, with ΦPL of up to 35%, and in solution, with ΦPL of up to 98%. We were able to correlate the powder photoluminescence quantum yields with the % Vbur of the P^P ligand. The most emissive complexes were used to fabricate both organic light-emitting diodes and light-emitting electrochem…

PhotoluminescenceLigandCationic polymerizationchemistry.chemical_element02 engineering and technologyBite angle010402 general chemistry021001 nanoscience & nanotechnologyElectrochemistry01 natural sciencesCopper0104 chemical sciencesInorganic ChemistryCrystallographychemistryElectrochemiluminescenceChelationPhysical and Theoretical Chemistry0210 nano-technologyInorganic chemistry
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Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(iii) complexes bearing bisphosphine ligands

2016

EZ-C acknowledges the University of St Andrews for financial support. We thank Johnson Matthey and Umicore AG for the gift of materials and Cihang Yu for the preparation of isopropxantphos. We thank Dr. Nail Shaveleev for the synthesis of NMS25. IDWS and AKB acknowledge support from EPSRC (EP/J01771X). This work has been supported by the Spanish Ministry of Economy and Competitiveness (MINECO) MAT2014-55200. Herein we present a structure-property relationship study of thirteen cationic iridium (III) complexes of the form of [Ir(C^N)2(P^P)]PF6 in both solution and the solid state through systematic evaluation of six bisphosphine (P^P) ligands (xantphos, dpephos, dppe, Dppe, nixantphos and is…

PhotoluminescenceXantphosLigandNDASCationic polymerizationchemistry.chemical_element02 engineering and technologyBite angleQD Chemistry010402 general chemistry021001 nanoscience & nanotechnologyPhotochemistryElectrochemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryQDIridium0210 nano-technologyLuminescenceInorganic Chemistry Frontiers
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CCDC 1423252: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographyCrystal System(bis(2-(Diphenylphosphino)phenyl) ether)-bis(2-(pyridin-2-yl)phenyl)-iridium hexafluorophosphate dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1423251: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters((99-Dimethyl-9H-xanthene-45-diyl)bis(diphenylphosphine))-bis(2-(pyridin-2-yl)phenyl)-iridium hexafluorophosphate dichloromethane solvate hemihydrateExperimental 3D Coordinates
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CCDC 2061123: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallography[(benzo[kl]xanthene-68-diyl)bis(diphenylphosphine)]-(29-dimethyl-110-phenanthroline)-copper(i) tetrafluoroborateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1423253: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographyCrystal SystemCrystal Structure(Ethene-12-diylbis(diphenylphosphine))-bis(2-(pyridin-2-yl)phenyl)-iridium hexafluorophosphate dichloromethane solvateCell ParametersExperimental 3D Coordinates
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CCDC 2061124: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(29-dimethyl-110-phenanthroline)-((ethene-12-diyl)-bis(diphenylphosphine))-copper tetrafluoroborate dichloromethane solvate
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CCDC 2061121: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallography[46-bis(diphenylphosphanyl)-10H-phenoxazine]-(29-dimethyl-110-phenanthroline)-copper(i) tetrafluoroborate dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2061118: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallographyCrystal System[(99-dimethyl-9H-xanthene-45-diyl)bis(diphenylphosphine)]-(29-dimethyl-110-phenanthroline)-copper(i) tetrafluoroborate dichloromethane diethyl ether solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1423259: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographybis(35-difluoro-2-(4-mesitylpyridin-2-yl)phenyl)-(ethene-12-diylbis(diphenylphosphine))-iridium hexafluorophosphate dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2061119: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallographyCrystal SystemCrystal Structure([1011-dihydrodibenzo[bf]oxepine-46-diyl)bis(diphenylphosphine)]-(29-dimethyl-110-phenanthroline)-copper(i) tetrafluoroborate dichloromethane solvateCell ParametersExperimental 3D Coordinates
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CCDC 1423255: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographybis(2-(4-Mesitylpyridyl)phenyl-CN)-((99-dimethyl-9H-xanthene-45-diyl)bis(diphenylphosphine))-iridium hexafluorophosphate dichloromethane diethyl ether solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1423254: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

(46-bis(Diphenylphosphino)-10H-phenoxazine)-bis(2-(pyridin-2-yl)phenyl)-iridium hexafluorophosphate dichloromethane solvate hemihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2061120: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallographyCrystal SystemCrystal Structure(29-dimethyl-110-phenanthroline)-{[9-(propan-2-ylidene)-9H-xanthene-45-diyl]bis(diphenylphosphine)}-copper(i) tetrafluoroborateCell ParametersExperimental 3D Coordinates
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Wide Bite Angle Disphosphine Ligands in Thermally Activated Delayed Fluorescent Copper(I) Complexes: Impact on the Performance of Electroluminescence…

2021

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CCDC 2061122: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(29-dimethyl-110-phenanthroline)-[(phenoxathiine-46-diyl)bis(diphenylphosphine)]-copper(i) tetrafluoroborateExperimental 3D Coordinates
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CCDC 1423258: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(35-difluoro-2-(4-mesitylpyridin-2-yl)phenyl)-((oxydi-21-phenylene)bis(diphenylphosphine))-iridium hexafluorophosphate diethyl ether solvateExperimental 3D Coordinates
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CCDC 1423257: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographyCrystal SystemCrystal Structurebis(35-difluoro-2-(4-mesitylpyridin-2-yl)phenyl)-((99-dimethyl-9H-xanthene-45-diyl)bis(diphenylphosphine))-iridium hexafluorophosphateCell ParametersExperimental 3D Coordinates
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CCDC 1423256: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographyCrystal SystemCrystal Structurebis(35-Difluoro-2-(pyridin-2-yl)phenyl-CN)-(ethene-12-diylbis(diphenylphosphine))-iridium hexafluorophosphate diethyl ether solvateCell ParametersExperimental 3D Coordinates
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