0000000001317214

AUTHOR

Pavel A. Abramov

showing 2 related works from this author

Mo 3 Q 7 (Q = S, Se) Clusters Containing Dithiolate/Diselenolate Ligands: Synthesis, Structures, and Their Use as Precursors of Magnetic Single‐Compo…

2013

The coordination chemistry of dithiolene and diselenolene ligands towards the all-selenium [Mo3Se7Br6]2– dianion has been investigated. Complexes (nBu4N)2[Zn(dmit)2] (dmit = 1,3-dithia-2-thioxo-4,5-dithiolate) and (nBu4N)2[Zn(dsit)2] (dsit = 1,3-dithia-2-thioxo-4,5-diselenolate) were employed as ligand precursors. The (nBu4N)2[Zn(dmit)2] complex in acetonitrile at reflux showed unexpected reactivity with [Mo3Se7Br6]2– dianion in which the inner Se atoms were replaced by S (all but the μ3-Se atom) to afford a series of mixed chalcogen [Mo3Se7–xSx(dmit)3]2– (x = 0–6) dianions. Reaction of the [Mo3S4Se3Br6]2– dianion with (nBu4N)2[Zn(dmit)2] under similar conditions also produced a mixed dmit-…

Molybdenumchemistry.chemical_classificationLigandInorganic chemistryCrystal structureCoordination complexConducting materialsInorganic ChemistrySeleniumchemistry.chemical_compoundCrystallographyChalcogenchemistryMagnetic propertiesCluster (physics)ChalcogensAntiferromagnetismReactivity (chemistry)AcetonitrileCluster compoundsEuropean Journal of Inorganic Chemistry
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CCDC 905329: Experimental Crystal Structure Determination

2013

Related Article: Artem L. Gushchin, Rosa Llusar, Cristian Vicent, Pavel A. Abramov, Carlos J. Gómez-Garcia|2013|Eur.J.Inorg.Chem.||2615|doi:10.1002/ejic.201201532

Space GroupCrystallographyCrystal SystemCrystal Structurebis(Tetra-n-butylammonium) (mu~3~-selenido)-bis(mu~2~-diselenolato)-(mu~2~-selanidethiolato)-tris(2-thioxo-13-dithiole-45-dithiolato)-tri-molybdenumCell ParametersExperimental 3D Coordinates
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