0000000001317215

AUTHOR

Ingrid Sanz

showing 2 related works from this author

Supramolecular assemblies and photophysical properties of ionic homo- and heteronuclear metallophilic complexes

2019

Abstract The synthesis of two dinuclear ionic complexes with chemical formula [Au(PR 3 ) 2 ][Au(C ≡ CC 5 H 4 N-4) 2 ] that contain the water soluble phosphines, PR 3 , PTA (1, 3,5-triaza-7-phosphaadamantane, 1 ) and DAPTA (3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, 2 ) is herein described. The differences on their intermolecular reorganization have been analyzed and compared with the previously reported for the neutral complexes [Au(PR 3 )(C ≡ CC 5 H 4 N-4)]. It has been evidenced that the reorganization of the ligands giving rise to the dinuclear ionic complexes produces a complete change in the properties giving rise to Au⋯Au intermolecular assemblies. These aurophilic conta…

010405 organic chemistryOrganic ChemistryIntermolecular forceSupramolecular chemistryIonic bondingOr010402 general chemistry01 natural sciencesBiochemistry0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryHeteronuclear moleculeHexafluorophosphateCompostos d'orMaterials ChemistryGoldPhysical and Theoretical ChemistryNonaneLuminescenceTrifluoromethanesulfonateGold compounds
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CCDC 1914062: Experimental Crystal Structure Determination

2019

Related Article: Noora Svahn, Ingrid Sanz, Kari Rissanen, Laura Rodríguez|2019|J.Organomet.Chem.|897|170|doi:10.1016/j.jorganchem.2019.07.001

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis((pyridin-4-yl)ethynyl)-bis(11'-(137-triaza-5-phosphabicyclo[3.3.1]nonane-37-diyl)bis(ethan-1-one))-di-goldExperimental 3D Coordinates
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